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材料科学与工程学院教师信息-石军教授


个人概况

3BE5

名:石

别:女

出生年月:197111

贯:河南省郑州市

最高学历:博

从事专业:有机高分子材料

务:教

称:教

联系方式:电话:0371-67781590

E-mailshijun@zzu.edu.cn

通讯地址:郑州市科学大道100号郑州大学材料科学与工程学院(邮政编码:450001

个人简历

19977月硕士毕业于长春工业大学化工系高分子化工专业;

20047月博士毕业于郑州大学化学系有机化学专业;

20054-20068月,葡萄牙Minho 大学3B研究室博士后研究员。从事高分子材料在生物医药领域的应用研究。

教学情况

先后承担有机化学、功能高分子、智能材料与生物医药应用、高分子材料、高分子化学实验等课程的讲授。

20099月获河南省师德先进个人称号,获河南省教育奖章;2009 9月获郑州大学第三届中青年教师讲课大赛一等奖;20099月获郑州大学三育人先进个人;200710月获郑州大学第二届中青年教师讲课大赛三等奖;郑州大学学生最为满意的授课教师。

研究领域

主要研究领域为智能性无机/高分子杂化微纳米材料的可控制备及其在生物医药领域的应用,近年来在智能性天然高分子基杂化药物释放材料、可降解高分子材料表面温敏聚合物的接枝反应、生物可降解基底表面的智能性仿生矿化层生长等领域进行了大量研究工作。主持国家自然科学基金、省教育厅自然科学基金等项目4项,通过省级以上鉴定3项;在国外著名期刊上发表学术论文40余篇,被SCI引用超过700次,影响因子3.0以上文章20篇,其中一篇文章作为Inside front cover page发表在Advanced Functional Materials上;另外一篇文章作为cover page发表在Macromolecular Bioscience上。撰写学术专著2部。2013年至今指导硕士研究生16名,其中7人获得研究生国家奖学金。

已完成项目如下:

1、河南省自然科学基金(No. 202300410475):天然高分子基协同增强光热响应纳米囊的可控构筑与界面相互作用,资助金额:10万,2020.01-2021.12,主持

2、河南省自然科学基金(No. 162300410257):羟基磷灰石基智能响应杂化微/纳米囊的仿生构筑与多重响应协同作用研究,资助金额:10万,2017.01-2018.12,主持

3国家自然科学基金(No.20874090):基于杂化海藻酸钙的天然高分子智能材料及其生物医用性能研究,资助金额:33万,2009.01-2011.12,主持

4河南省教育厅自然科学基金(No.2008A430018):仿生矿化聚糖膜增强海藻酸基双敏微球的可控药物释放研究,资助金额:1, 主持

52009年度河南省高校青年骨干教师资助计划:无机-有机杂化天然高分子材料的智能药物释放研究,2010.01-2012.12,主持。

主要荣誉

1、河南省师德先进个人,获河南省教育奖章(河南省教育工会,2009年)

2、河南省教育厅学术技术带头人(2011年)

3、河南省中青年骨干教师(河南省教育厅、人事厅,2009年)

4、郑州大学三育人先进个人(郑州大学工会,2009年)

成果清单

1. 发表论文

1. C.C. Liu, P.P. Yang, J.G. Li, S. Cao, J. Shi*, “NIR/pH-responsive chitosan hydrogels containing Ti3C2/AuNRs with NIR-triggered photothermal effect”, Carbohyd. Polym. 2022, 295, 119853.(注: *为通讯作者)

2. P.A. Song, W.Y. Wang, J.G. Li, S.K. Cao, J. Shi*, “Self-assembly of hydroxyapatite around Ti3C2 MXene/gold nanorods for efficient remotely triggered drug delivery”, Ceram. Int. 2022, 48, 27957-27966.

3. R.X. Chen, J. Shi*, Chongchong Liu, J.G. Li, S.K. Cao*, “In situ self-assembly of gold nanorods with thermal-responsive microgel for multi-synergistic remote drug delivery”, Adv. Compos. Hybrid Mater. 2022, 5, 2223-2234.

4. Z. Wu, J. Shi*, P.A. Song, J.G. Li, S.K. Cao*, “Chitosan/hyaluronic acid based hollow microcapsules equipped with MXene/gold nanorods for synergistically enhanced NIR responsive drug delivery”, Int. J. Biol. Macromol. 2021, 183, 870-879.

5. B.B. Zhu, J. Shi*, C.C. Liu, J.G. Li, S.K. Cao*, “In-situ self-assembly of sandwich-like Ti3C2 MXene/gold nanorods nanosheets for synergistically enhanced near-infrared responsive drug delivery”, Ceram. Int. 2021, 47, 24252-24261.

6. R.X. Chen, J. Shi*, B.B. Zhu, L. Zhang, S.K. Cao*, “Mesoporous hollow hydroxyapatite capped with smart polymer for multi-stimuli remotely controlled drug delivery”, Microp. Mesop. Mater. 2020, 306, 110447.

7. Y.C. Cao, J. Shi*, Z. Wu, J.G. Li, S.K. Cao*, “Gold nanorods/polydopamine-capped hollow hydroxyapatite microcapsules as remotely controllable multifunctional drug delivery platform”, Powder Technol. 2020, 372, 486-496.

8. Z.E Qi, J. Shi*, B.B. Zhu, J.G. Li, S.K. Cao*, “Gold nanorods/graphene oxide nanosheets immobilized by polydopamine for efficient remotely triggered drug delivery”, J. Mater. Sci. 2020, 55(29), 14530-14543.

9. Z.E. Qi, J. Shi*, Z. Zhang, Y.C. Cao, J.G. Li, S.K. Cao*, “PEGylated graphene oxide-capped gold nanorods/silica nanoparticles as multifunctional drug delivery platform with enhanced near-infrared responsiveness”, Mater. Sci. Eng. C 2019, 104, 109889.

10. X.Y. Zhu, J. Shi*, H. Ma, R.X. Chen, J.G. Li, S.K. Cao*, “Hierarchical hydroxyapatite/polyelectrolyte microcapsules capped with AuNRs for remotely triggered drug delivery”, Mater. Sci. Eng. C 2019, 99, 1236-1245.

11. H. Ma, J. Shi*, X.Y. Zhu, Z. Zhang, J.G. Li, S.K. Cao*, “AuNRs/mesoporous silica/hydroxyapatite nanovehicles with thermally responsive polymeric cap for remotely controlled drug delivery”, Adv. Compos. Hybrid Mater. 2019, 2, 242-253.

12. Z. Zhang, J. Shi*, Z.X. Song, X.Y. Zhu, Y.P. Zhu, S.K. Cao*, “A synergistically enhanced photothermal transition effect from mesoporous silica nanoparticles with gold nanorods wrapped in reduced graphene oxide”, J. Mater. Sci. 2018, 53, 1810-1823.

13. Z.X. Song, Y. Liu, J. Shi*, T. Ma, Z. Zhang, H. Ma, S.K. Cao*, “Hydroxyapatite/mesoporous silica coated gold nanorods with improved degradability as a multi-responsive drug delivery platform”, Mater. Sci. Eng. C 2018, 83, 90-98.

14. Z.X. Song, J. Shi*, Z. Zhang, Z.E. Qi, S.R. Han, S.K. Cao*, “Mesoporous silica-coated gold nanorods with a thermally responsive polymeric cap for near infrared-activated drug delivery”, J. Mater. Sci. 2018, 53, 7165-7179.

15. Y.P. Zhu, N. Li, T. Lv, Y. Yao, H.N. Peng, J. Shi*, S. Cao*, T. Chen*, “Ag-Doped PEDOT: PSS/CNT composites for thin-film all-solid-state supercapacitors with a stretchability of 480%”, J. Mater. Chem. A 2018, 6, 941-947.

16. J. Shi*, X.J. Wang, S.H. Xu, Q. Wu, S.K. Cao*, “Reversible thermal-tunable drug delivery across nano-membranes of hollow PUA/PSS multilayer microcapsules”, J. Membr. Sci. 2016, 499, 307-316.

17. S.H. Xu, J. Shi*, D.S. Feng, L. Yang, S.K. Cao*, “Hollow PUA/PSS/Au microcapsules with interdependent near-infrared/pH/temperature multiresponsiveness”, J. Appl. Polym. Sci. 2016, 133, 43008.

18. J. Wei, J. Shi*, Q. Wu, L. Yang, S.K. Cao*, “Hollow hydroxyapatite/polyelectrolyte hybrid microparticles with controllable size, wall thickness and drug delivery property”, J. Mater. Chem. B 2015, 3, 8162-8169.

19. Q. Wu, J. Shi*, J. Wei, L. Yang, S.K. Cao*, “In situ functionalization of hollow mesoporous hydroxyapatite with thermal-responsive on-off gates in supercritical CO2”, RSC Advances 2015, 5, 70101- 70108.

20. L. Yang, J. Shi*, X.F. Zhou, S.K. Cao*, “Hierarchically organization of biomineralized alginate beads for dual stimuli-responsive drug delivery”, Int. J. Biol. Macromol. 2015, 73, 1-8.

21. S.H. Xu, J. Shi*, D.S. Feng, L. Yang, S.K. Cao*, “Hollow hierarchical hydroxyapatite/Au/

polyelectrolyte hybrid microparticles for multi-responsive drug delivery”, J. Mater. Chem. B 2014, 2, 6500-6507.

22. J. Shi*, L. Zhang, Y.L. Liu, S.G. Xu, S.K. Cao*, “Biomineralized organic-inorganic hybrids aiming for smart drug delivery”, Pure Appl. Chem. 2014, 86, 671-683.

23. J. Shi, J. Shi*, D.S. Feng, P. Yue, S.K. Cao*, “Stimuli-responsive hybrid composites based on CaCO3 microparticles and smart polyelectrolytes for controllable drug delivery”, Polym. Bull. 2014, 71, 1857-1873.

24. D.S. Feng, J. Shi*, X.J. Wang, L. Zhang, S.K. Cao*, “Hollow hybrid hydroxyapatite microparticles with sustained and pH-responsive drug delivery properties”, RSC Advances 2013, 3, 24975-24982.

25. J. Shi*, C. Du, J. Shi, Y.M. Wang, S.K. Cao*, “Hollow multilayer microcapsules for pH-/thermal-responsive drug delivery using aliphatic poly(urethane-amine) as smart component”,

Macromol. Biosci. 2013, 13, 494-502.

26. J. Shi*, J. Shi, C. Du, Q. Chen, S.K. Cao*, “Thermal and pH dual responsive alginate/CaCO3 hybrid membrane prepared under compressed CO2”, J. Membr. Sci. 2013, 433, 39-48.

27. C. Du, J. Shi*, J. Shi, L. Zhang, S.K. Cao*, “PUA/PSS multilayer coated CaCO3 microparticles as smart drug delivery vehicles”, Mater. Sci. Eng. C 2013, 33, 3745-3752.

28. J. Shi*, W.Y. Qi, C. Du, J. Shi, S.K. Cao*, “Micro/nano hybrid hierarchical PNIPAAm/calcium carbonate composites for smart drug delivery”, J. Appl. Polym. Sci. 2013, 129, 577-584.

29. X.M. Sun, J. Shi*, X.D. Xu, S.K. Cao*, “Chitosan coated alginate/poly(N-

isopropylacrylamide) beads for dual responsive drug delivery”, Int. J. Biol. Macromol.2013, 59, 273-281.

30. J. Shi*, W.Y. Qi, G.F. Li, S.K. Cao*, “Biomimetic self-assembly of calcium phosphate templated by PNIPAAm nanogels for sustained smart drug delivery”, Mater. Sci. Eng. C 2012, 32, 1299-1306.

31. J. Shi*, Z.Z. Zhang, W.Y. Qi, S.K. Cao*, “Hydrophobically modified biomineralized polysaccharide alginate membrane for sustained smart drug delivery”, Int. J. Biol. Macromol. 2012, 50, 747-753.

32. J. Shi*, Z.Z. Zhang, G.F. Li, S.K. Cao*, “Biomimetic fabrication of alginate/CaCO3 hybrid beads for dual-responsive drug delivery under compressed CO2”, J. Mater. Chem. 2011, 21, 16028-16034.

33. J. Shi*, X.P. Liu, X.M. Sun, S.K. Cao*, “Hybrid alginate beads with thermal-responsive gates for smart drug delivery”, Polym. Adv. Technol. 2011, 22, 1539-1546.

34. X.M. Sun, J. Shi*, Z.Z. Zhang, S.K. Cao*, “Dual-responsive semi-IPN beads based on Ca-alginate/ PNIPAAm/PAANa for sustained drug release”, J. Appl. Polym. Sci. 2011,

122, 729-737.

35. J. Shi*, X.P. Liu, S.K. Cao*, “Biomineralized polysaccharide alginate membrane for multi-responsive controlled delivery”, J. Membr. Sci., 2010, 352, 262-270.

36. N.M. Alves, J. Shi, O. Elena, et al, “Bioinspired superhydrophobic poly(L-lactic acid) surfaces control bone marrow derived cells adhesion and proliferation”, J. Biomed. Mater. Res. Part A, 2009, 91A (2), 480-488.

37. J. Shi*, L.H. Liu, X.M. Sun, S.K. Cao*, “Biomineralized polysaccharide beads for dual-stimuli-responsive drug delivery”, Macromol. Biosci., 2008, 8, 260-267.

38. J. Shi, N.M. Alves, J.F. Mano, “Chitosan-alginate multilayer beads containing Poly (N-isopropyl- acrylamide) for dual-stimuli-responsive drug release”, J. Biomed. Mater. Res. Part B, 2008, 84B (2), 595-603.

39. J. Shi*, L.H. Liu, X.P. Liu, S.K. Cao*, “Inorganic-organic hybrid alginate beads with LCST near human body temperature for sustained dual-sensitive drug delivery”, Polym. Adv. Technol., 2008, 19, 1467-1473.

40. J. Shi, N.M. Alves, J.F. Mano, “Towards bioinspired superhydrophobic poly(L-lactic acid) surfaces using phase inversion-based methods”, Bioinspiration and Biomimetics, 2008, 3, 1-6.

41. L. Zhang, J. Shi, Z.W. Jiang, S.K. Cao, Photorefractive performance of hyperstructured cyclotriphosphazene molecular glasses containing carbazole moieties”, Adv. Funct. Mater., 2008, 18: 362-368.

42. L. Zhang, J. Shi, Z. Yang, S.K. Cao, “Photorefractive properties of polyphosphazenes containing carbazole-based multifunctional chromophores”, Polymer, 2008, 49: 2107-2114.

43. J. Shi, N.M. Alves, J.F. Mano, “Thermally smart temperature-responsive biomineralization onto biodegradable polymeric substrates”, Adv. Funct. Mater., 2007, 17, 3312-3318.

44. J. Shi, N.M. Alves, J.F. Mano, “Drug release behaviour of pH/temperature responsive semi-  IPN beads composed of calcium alginate and poly (N-isopropylacrylamide)”, Macromol. Biosci., 2006, 6, 358-363.

2.学术专著

1《有机光折变材料》,科学出版社,2009年,ISBN978-7-03-025436-8.

2Jun Shi and Shaokui Cao, “Synthesis of carbazole-based functionalized polymers via a postfunctionalization strategy”, Leading Edge Polymer Research, Nova Science Publishers, chapter 6, 191-212 (2006).

 

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