个人简介
高其龙,副教授,博士生导师,河南省优青、郑州大学青年拔尖人才,河南周口人。019年以校青年拔尖人才计划进入郑州大学物理学院工作,2020年被聘为副教授和博/硕士生导师。目前主持国家自然科学基金青年项目和面上项目各一项,主持河南省自然科学基金优青项目,主持中国博士后面上基金一项。发表SCI论文40篇,其中以第一作者或通讯作者身份发表25篇SCI论文在J.Am.Chem.Soc.、Angew.Chem.Int.Ed.、Nat.Commun、Sci. China Matter.、Scripta. Matter.、Inorg.Chem.、Appl.Phys.Lett.等学术期刊。目前主要进行负热膨胀材料结构设计与机制研究。在同步辐射、中子散射等大装置开展研究(美国APS、NIST,英国ISIS,日本Spring-8,意大利Elettra等),相关成果发表在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commun等SCI学术期刊。其中,通过对ZrV2O7结构设计实现其NTE温区延伸到室温以下,被APL选为Feature Article,并被美国物理学联合会AIP Scilight专访报道;设计“平均原子晶格体积”新概念为探索新NTE体系提供新方法,被JACS Spotlight重点推介;设计客体嵌入热膨胀的调控新方法,被意大利ELETTRA光源官网报道,并收录于2017年年度ELETTRA Highlights和ESRF Highlights。
邮箱:qilonggao@zzu.edu.cn
科研方向
负热膨胀材料设计与机制研究
光催化与电催化机理研究
储能材料晶体结构研究
光学与光电材料设计与制备
教育背景与工作简历
2009-2013年:辽宁科技大学材料化学(本科)
2013-2019年:北京科技大学冶金物理化学(硕博连读)
2019年-至今:郑州大学物理工程学院,副教授,硕/博士生导师
科研项目
主持:国家自然科学基金面上项目(2021-2024)
主持:河南省自然科学优青基金(2021-2023)
主持:国家自然科学青年基金(2020-2022)
主持:博士后面上基金(2019-2020)
主持:郑州大学青年拔尖人才项目(2019-2021)
学术论文(部分)
1. Q.L. Gao, J. Wang, A. Sanson, Q. Sun, E.J. Liang*, X.R. Xing, and J. Chen*. Discovering Large Isotropic Negative Thermal Expansion in Framework Compound AgB(CN)4 via the Concept of Average Atomic Volume. J. Am. Chem. Soc., 142, 6935−6939 (2020).
2. Q.L. Gao, J. Chen*, Q. Sun, D.H. Chang, Q.Z. Huang, H. Wu, A. Sanson, R. Milazzo, H. Zhu, Q. Li, Z.N. Liu, J.X. Deng and X.R. Xing, Switching Between Giant Positive and Negative Thermal Expansions of a YFe(CN)6-based Prussian Blue Analogue Induced by Guest Species Angew. Chem. Int. Ed., 56, 9023-9028. (2017)
3. J. Chen(导师第一作者), Q.L. Gao, A. Sanson, X.X. Jiang, Q.Z. Huang, A. Carnera, C.G. Rodriguez, L. Olivi, L. Wang, L. Hu, K. Lin, Y. Ren, Z.S. Lin, C. Wang, L. Gu, J.X. Deng, J.P. Attfield*, X.R. Xing*. Tunable Thermal Expansion in Framework Materials through Redox Intercalation. Nat. Commun., 8, 14441 (2017)
4. H. Yuan, C. Wang, Q.L. Gao*, X. Ge, H. Sun, S. H. Lapidus, J. Guo, M. Chao, Y. Jia, E.J. Liang*. Structure and Negative Thermal Expansion in Zr0.3Sc1.7Mo2.7V0.3O12. Inorg. Chem., 59, 4090-4095 (2020).
5. W. Wei, Q.L. Gao*, J. Guo, M. Chao, L. He, J. Chen, and E.J. Liang*. Realizing Isotropic Negative Thermal Expansion Covering Room Temperature by Breaking the Superstructure of ZrV2O7. Appl. Phys. Lett., 116, 181902 (2020).
6. Q.L. Gao, J. Chen*, Q. Li, J. Zhang, Z. Zhai, S.T. Zhang, R.B. Yu and X. R. Xing, Structure and Excellent Visible Light Catalysis of Prussian Blue Analogues BiFe(CN)6×4H2O. Inorg. Chem. Front., 5, 438-445 (2018).
7. Q.L. Gao, N, Shi, Q, Sun, A, Sanson, R. Milazzo, A, Carnera, H. Zhu, S.H. Lapidus, Y. Ren, Q.Z. Huang, J. Chen*, and X.R. Xing, Low-Frequency Phonon Driven Negative Thermal Expansion in Cubic GaFe(CN)6 Prussian Blue Analogues. Inorg. Chem., 57, 10918–10924 (2018)
8. Q.L. Gao, N, Shi, A, Sanson, Y. Sun, R. Milazzo, L, Olivi, H, Zhu, S.H. Lapidus, L. Zheng, J. Chen*, and X.R. Xing. Tunable Thermal Expansion from Negative, Zero, to Positive in Cubic Prussian Blue Analogues of GaFe(CN)6. Inorg. Chem., 57, 14027–14030 (2018).
9. Q.L. Gao, E.J. Liang, X.R. Xing, and J. Chen*. Negative Thermal Expansion in Prussian Blue Analogues. Chem. J. Chinese U., 41, 388-400 (2020).
10. Q.L. Gao, Y. Sun, N. Shi, R. Milazzo, S. Pollastri, L. Olivi, Q. Huang, H. Liu, A. Sanson*, Q. Sun*, E.J. Liang, X.R. Xing, and J. Chen*. Large isotropic negative thermal expansion in water-free Prussian blue analogues of ScCo(CN)6. Scripta Mater., 187, 119-124 (2020).
11. Y. Li, Q.L. Gao*, D. Chang, P. Sun, J. Liu, Y. Jia, E. Liang and Q. Sun. Effect of bond on negative thermal expansion of Prussian blue analogues MCo(CN)6(M = Fe, Ti and Sc): a first-principles study. J. Phys.: Condens. Matter. 32, 455703 (2020).
12.Qilong Gao, Xinwei Shi, Alessandro Venier, Alberto Carnera, Qingzhen Huang, Jun Chen*, Andrea Sanson*, Erjun Liang* The Effect of H2O Molecules on Thermal Expansion of TiCo(CN)6, Inorg. Chem., 2020, Doi: 10.1021/acs.inorgchem.0c02029.
13. C. Wang, D. Chang, Q.L. Gao*, C. Liu, Q. Wang, X. Huang and Y. Jia. Large and tunable negative thermal expansion induced by a synergistic effect in M2II[MIV(CN)8] Prussian blue analogues. Phys. Chem. Chem. Phys., 22, 18655 (2020).
14. Yaxing Gao, Chunyan Wang, Q.L. Gao,* Juan Guo, Mingju Chao, Yu Jia, and Erjun Liang. Zero Thermal Expansion in Ta2Mo2O11 by Compensation Effects. Inorg. Chem. 59, 18427−18431 (2020).
15. Qilong Gao*, Qiang Sun, Alessandro Venier, Andrea Sanson, Qingzhen Huang, Yu Jia, Erjun liang and Jun Chen* The role of average atomic volume in predicting negative thermal expansion: The case of REFe(CN)6, Sci. China Mater., 65, 553-557(2021).
16. Huanli Yuan, Qilong Gao,* Peng Xu, Juan Guo, Lunhua He, Andrea Sanson, Mingju Chao, and Erjun Liang*, Understanding Negative Thermal Expansion of Zn2GeO4 through Local Structure and Vibrational Dynamics. Inorg. Chem. 60, 1499−1505 (2021).
17. Jiaqi Wang, Qilong Gao*, Yaxing Gao, Yan Luo, Juan Guo, Qiang Sun, and Erjun Liang*. Uniaxial negative thermal expansion behavior of beta-CuSCN, Appl. Phys. Lett. 118, 222105 (2021)
18. Pengju Sun, Qilong Gao*, Junzhe Liu, Erjun Liang and Qiang Sun* Theoretical Study of Abnormal Thermal Expansion of CuSCN and Effect on Electronic Structure, Front. Mater. 8:712395 (2021).
19. Mingyue Zhang, Chunyan Wang, Yinuo Zhang, Qilong Gao*, Yu Jia*. Negative thermal expansion in NbF3 and NbOF2: A comparative theoretical study. Chinese Physics B 30 (5), 056501 (2021).
20. Yan Luo, Yongqiang Qiao*, Qilong Gao*, Jiaqi Wang, Juan Guo, Xiao Ren, Mingju Chao, Qiang Sun, Yu Jia, and Erjun Liang* Anomalous Thermal Expansion in Ta2WO8 Oxide Semiconductor over a Wide Temperature Range Inorg. Chem. 60, 17758−17764 (2021).