高其龙，副教授，博士生导师，河南省优青、郑州大学青年拔尖人才，河南周口人。019年以校青年拔尖人才计划进入郑州大学物理学院工作，2020年被聘为副教授和博/硕士生导师。目前主持国家自然科学基金青年项目和面上项目各一项，主持河南省自然科学基金优青项目，主持中国博士后面上基金一项。发表SCI论文40篇，其中以第一作者或通讯作者身份发表25篇SCI论文在J.Am.Chem.Soc.、Angew.Chem.Int.Ed.、Nat.Commun、Sci. China Matter.、Scripta. Matter.、Inorg.Chem.、Appl.Phys.Lett.等学术期刊。目前主要进行负热膨胀材料结构设计与机制研究。在同步辐射、中子散射等大装置开展研究（美国APS、NIST，英国ISIS，日本Spring-8，意大利Elettra等），相关成果发表在J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commun等SCI学术期刊。其中，通过对ZrV₂O₇结构设计实现其NTE温区延伸到室温以下，被APL选为Feature Article，并被美国物理学联合会AIP Scilight专访报道；设计“平均原子晶格体积”新概念为探索新NTE体系提供新方法，被JACS Spotlight重点推介；设计客体嵌入热膨胀的调控新方法，被意大利ELETTRA光源官网报道，并收录于2017年年度ELETTRA Highlights和ESRF Highlights。

邮箱：qilonggao@zzu.edu.cn

科研方向

负热膨胀材料设计与机制研究

光催化与电催化机理研究

储能材料晶体结构研究

光学与光电材料设计与制备

教育背景与工作简历

2009-2013年：辽宁科技大学材料化学（本科）

2013-2019年：北京科技大学冶金物理化学（硕博连读）

2019年-至今：郑州大学物理工程学院，副教授，硕/博士生导师

科研项目

主持：国家自然科学基金面上项目（2021-2024）

主持：河南省自然科学优青基金（2021-2023）

主持：国家自然科学青年基金（2020-2022）

主持：博士后面上基金（2019-2020）

主持：郑州大学青年拔尖人才项目（2019-2021）

学术论文（部分）

1.Q.L. Gao, J. Wang, A. Sanson, Q. Sun,E.J. Liang*,X.R. Xing, and J. Chen*.Discovering Large Isotropic Negative Thermal Expansion in Framework Compound AgB(CN)₄via the Concept of Average Atomic Volume.J. Am. Chem. Soc.,142, 6935−6939 (2020).

2.Q.L. Gao,J. Chen*, Q. Sun, D.H. Chang, Q.Z. Huang, H. Wu, A. Sanson, R. Milazzo, H. Zhu, Q. Li, Z.N. Liu, J.X. Deng and X.R. Xing,Switching Between Giant Positive and Negative Thermal Expansions of a YFe(CN)₆-based Prussian Blue Analogue Induced by Guest SpeciesAngew. Chem. Int. Ed.,56, 9023-9028. (2017)

3.J. Chen(导师第一作者),Q.L. Gao, A. Sanson, X.X. Jiang, Q.Z. Huang, A. Carnera, C.G. Rodriguez, L. Olivi, L. Wang, L. Hu, K. Lin, Y. Ren, Z.S. Lin, C. Wang, L. Gu, J.X. Deng, J.P. Attfield*, X.R. Xing*. Tunable Thermal Expansion in Framework Materials through Redox Intercalation.Nat. Commun.,8, 14441 (2017)

4.H. Yuan, C. Wang,Q.L. Gao*, X. Ge, H. Sun, S. H. Lapidus, J. Guo, M. Chao, Y. Jia, E.J. Liang*. Structure and Negative Thermal Expansion in Zr_0.3Sc_1.7Mo_2.7V_0.3O₁₂.Inorg. Chem.,59,4090-4095(2020).

5.W. Wei,Q.L. Gao*, J. Guo, M. Chao, L. He,J. Chen, andE.J. Liang*.Realizing Isotropic Negative Thermal Expansion Covering Room Temperature by Breaking the Superstructure of ZrV₂O₇.Appl. Phys. Lett.,116, 181902 (2020).

6.Q.L. Gao,J. Chen*, Q. Li, J. Zhang, Z. Zhai, S.T. Zhang, R.B. Yuand X. R. Xing, Structure and Excellent Visible Light Catalysis of Prussian Blue Analogues BiFe(CN)₆×4H₂O.Inorg. Chem. Front.,5, 438-445(2018).

7.Q.L. Gao,N, Shi,Q, Sun,A, Sanson,R. Milazzo,A, Carnera,H. Zhu,S.H. Lapidus,Y. Ren,Q.Z. Huang,J. Chen*, andX.R. Xing,Low-Frequency Phonon Driven Negative Thermal Expansion in Cubic GaFe(CN)₆Prussian Blue Analogues.Inorg. Chem.,57,10918–10924 (2018)

8.Q.L. Gao,N, Shi,A, Sanson,Y. Sun,R. Milazzo, L, Olivi, H, Zhu,S.H. Lapidus, L. Zheng,J. Chen*, and X.R. Xing.Tunable Thermal Expansion from Negative, Zero, to Positive inCubic Prussian Blue Analogues of GaFe(CN)₆.Inorg. Chem.,57, 14027–14030 (2018).

9.Q.L. Gao,E.J. Liang,X.R. Xing, and J. Chen*.Negative Thermal Expansion in Prussian Blue Analogues.Chem. J. Chinese U.,41, 388-400 (2020).

10.Q.L. Gao, Y. Sun, N. Shi, R. Milazzo, S. Pollastri, L. Olivi, Q. Huang, H. Liu,A.Sanson*,Q. Sun*,E.J. Liang,X.R. Xing, and J. Chen*.Large isotropic negative thermal expansion in water-free Prussian blue analogues of ScCo(CN)₆.Scripta Mater.,187, 119-124 (2020).

11.Y. Li,Q.L. Gao*, D. Chang, P. Sun, J. Liu, Y. Jia, E. Liang and Q. Sun. Effect of bond on negative thermal expansion of Prussian blue analogues MCo(CN)₆(M = Fe, Ti and Sc): a first-principles study.J. Phys.: Condens. Matter.32, 455703(2020).

12.Qilong Gao, Xinwei Shi, Alessandro Venier, Alberto Carnera, Qingzhen Huang, Jun Chen^*, Andrea Sanson^*, Erjun Liang^*The Effect of H₂O Molecules on Thermal Expansion of TiCo(CN)6,Inorg. Chem.,2020, Doi: 10.1021/acs.inorgchem.0c02029.

13.C. Wang, D. Chang,Q.L. Gao*,C. Liu, Q. Wang, X. Huang and Y. Jia. Large and tunable negative thermal expansion induced by a synergistic effect in M₂^II[M^IV(CN)₈] Prussian blue analogues.Phys. Chem. Chem. Phys.,22, 18655(2020).

14.Yaxing Gao, Chunyan Wang,Q.L. Gao,*Juan Guo, Mingju Chao, Yu Jia, and Erjun Liang.Zero Thermal Expansion in Ta2Mo2O11 by Compensation Effects.Inorg. Chem.59, 18427−18431 (2020).

15.Qilong Gao*,Qiang Sun, Alessandro Venier, Andrea Sanson, Qingzhen Huang, Yu Jia, Erjun liang and Jun Chen*The role of average atomic volume in predicting negative thermal expansion: The case ofREFe(CN)₆,Sci. China Mater.,65, 553-557(2021).

16.Huanli Yuan,Qilong Gao,*Peng Xu, Juan Guo, Lunhua He, Andrea Sanson, Mingju Chao, and Erjun Liang*, Understanding Negative Thermal Expansion of Zn₂GeO₄through Local Structure and Vibrational Dynamics.Inorg. Chem.60, 1499−1505(2021).

17.Jiaqi Wang,Qilong Gao*,Yaxing Gao, Yan Luo, Juan Guo, Qiang Sun, and Erjun Liang*. Uniaxial negative thermal expansion behavior of beta-CuSCN,Appl. Phys. Lett.118, 222105 (2021)

18.Pengju Sun,Qilong Gao*,Junzhe Liu,Erjun LiangandQiang Sun* Theoretical Study of Abnormal Thermal Expansion of CuSCN and Effect on Electronic Structure,Front. Mater.8:712395(2021).

19.Mingyue Zhang, Chunyan Wang, Yinuo Zhang,Qilong Gao*, Yu Jia*. Negative thermal expansion in NbF₃and NbOF₂: A comparative theoretical study.Chinese Physics B30 (5), 056501(2021).

20.Yan Luo, Yongqiang Qiao*,Qilong Gao*, Jiaqi Wang, Juan Guo, Xiao Ren, Mingju Chao, Qiang Sun, Yu Jia, and Erjun Liang* Anomalous Thermal Expansion in Ta2WO8 Oxide Semiconductor over a Wide Temperature RangeInorg. Chem.60, 17758−17764(2021).