华远照

作者: 时间:2021-01-14 点击数:

华远照,郑州大学,化学与分子工程学院,讲师。男,汉族,1979年07月生于河南省南阳市。

教育经历:

2011/09—2015/07:郑州大学化学与分子工程学院,有机化学博士,导师:常俊标教授;

2002/09—2005/07:郑州大学化学系,有机化学硕士,导师:王敏灿教授;

1998/09—2002/07:郑州大学化学系,化学本科;

科研与学术工作经历:

2017/09—至今,郑州大学,药学院,博士后,合作导师:杨华

2016/08—至今,郑州大学,化学与分子工程学院,讲师

2008/07—2011/09,新乡医学院,基础医学院,讲师;

2005/07—2008/07,新乡医学院,基础医学院,助教;

主持或参加科研项目(课题)及人才计划项目情况:

1.国家自然科学基金面上项目,21871237,双核锌协同催化的不对称串联反应研究,2019/01—2022/12,65万元,在研,参与

2.中国博士后科学基金面上二等资助,2017M622361,半冠状多齿双噁唑啉手性配体的设计、合成及应用,2018/01-2019/12,5万元,已结项,主持

3.国家自然科学基金面上项目,21272216,二氧化碳与环氧化物的催化不对称交替共聚反应研究,2012/01—2016/12,80万元,已结项,参与

代表性研究成果和学术奖励情况

期刊论文

1.Yuan-Zhao Hua, Xing-Wang Han, Xiao-Chao Yang, Xixi Song, Min-Can Wang(*), and Jun-Biao Chang(*). Enantioselective Friedel−Crafts Alkylation of Pyrrole with Chalcones Catalyzed by a Dinuclear Zinc Catalyst[J].J. Org. Chem.2014,79, 11690–11699.

2.Yuan-Zhao Hua,Liu-Jie Lu, Pei-Jin Huang, Dong-Hui Wei, Ming-Sheng Tang, Min-Can Wang(*), and Jun-Biao Chang(*). Highly Enantioselective Catalytic System for Asymmetric Copolymerization of Carbon Dioxide and Cyclohexene Oxide[J].Chem.Eur. J.2014,20, 12394–12398.

3.Yuan-Zhao Hua, Meng-Meng Liu, Pei-Jin Huang, Xi-Xi Song, Min-Can Wang(*), and Jun-Biao Chang(*).A New Strategy for Enantioselective Construction of Multisubstituted Five-Membered Oxygen Heterocycles via a Domino Michael/Hemiketalization Reaction[J].Chem.Eur. J.2015,21, 11994–11998.

4.Yuan-Zhao Hua, Xiao-Chao Yang, Meng-Meng Liu, Xixi Song, Min-Can Wang(*)and Jun-BiaoChang(*).Asymmetric Copolymerization ofCyclopenteneOxide and CO2Using a Dinuclear Zinc-AzePhenol Catalyst:Enlightenedby DFT Calculations[J].Macromolecules2015,48, 1651–1657.

5. Xin-Wei Wang,Yuan-Zhao Hua(*), Min-Can Wang(*). Synthesis of 3-IndolylglycineDerivatives via Dinuclear Zinc Catalytic Asymmetric Friedel-Crafts Alkylation Reaction[J].J. Org. Chem.2016,81, 9227–9234.

6.Yuan-Zhao Hua,Xing-Wang Han, Li-Hua Huang(*),Min-Can Wang(*). Asymmetric Friedel-Crafts Alkylation of Pyrrole with Chalcones Catalyzed by a Dinuclear Zinc Catalyst[J].Chin.J. Org. Chem.2018,38, 237–248.

7. Na Shao, Yong-Yang Luo, Hui-Jie Lu,Yuan-Zhao Hua(*), Min-Can Wang(*). Enantioselective phospha-Michael reaction of diethyl phosphonate with exocyclic α,β-unsaturated benzocyclic ketones catalyzed by a dinuclear zinc−AzePhenol catalyst[J].Tetrahedron2018,74, 2130-2142.

8. Yuan-Yuan Gao,Yuan-Zhao Hua(*), Min-Can Wang(*). Asymmetric 1,6-Conjugate Addition of para-Quinone Methides for the Synthesis of Chiral β,β-Diaryl-α-Hydroxy Ketones[J].Adv. Synth. Catal.2018,360, 80–85.

9.Yuan-Zhao Hua, Jun-Wei Chen, Hua Yang(*), and Min-Can Wang(*). Asymmetric Friedel–Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst[J].J. Org. Chem.2018,83, 1160–1166.

10.Yu-Hang Miao,Yuan-Zhao Huaand Min-Can Wang(*). Dinuclear zinc cooperative catalytic three-component reactions for highly enantioselective synthesis of 3,3’-dihydrofuran spirooxindoles[J].Org. Biomol. Chem.2019,17, 7172–7181.

11. Bing-Kai Tao, Hua Yang,Yuan-Zhao Hua(*), Min-Can Wang(*). Dinuclear zinc synergistic catalytic asymmetric phospha-Michael/Michael cascade reaction: synthesis of 1,2,3-trisubstituted indanes bearing phosphoryl groups[J].Org. Biomol. Chem.2019,17, 4301−4310.

12.Meng-Meng Liu, Xiao-Chao Yang,Yuan-Zhao Hua, Jun-Biao Chang(*),Min-Can Wang(*). Synthesis of Chiral Bispirotetrahydrofuran Oxindoles by Cooperative Bimetallic-Catalyzed Asymmetric Cascade Reaction[J].Org. Lett.2019,21, 2111−2115.

13.Meng-Meng Liu, Xiao-Chao Yang,Yuan-Zhao Hua,(*)Jun-Biao Chang(*),Min-Can Wang.(*)Dinuclear Zinc-Catalyzed Asymmetric Tandem Reaction of α-Hydroxy-1-indanone: Access to Spiro[1-indanone-5,2′-γ-butyrolactones][J].Org. Lett.2019,21, 7089-7093.

14.Xiao-Chao Yang, Meng-Meng Liu, François Mathey, Hua Yang,Yuan-Zhao Hua(*),Min-Can Wang(*). Access to Chiral 2,5-Pyrrolidinyl Dispirooxindoles via Dinuclear Zinc-Catalyzed Asymmetric Cascade Reactions[J].J. Org. Chem.2019,84, 7762−7775.

15. Ya-Jun Guo, Xin Guo, De-Zhi Kong, Hui-Jie Lu, Lan-Tao Liu,Yuan-Zhao Hua,(*)and Min-Can Wang(*). Catalytic Asymmetric Synthesis of Tetrahydrofuran Spirooxindoles 2 via a Dinuclear Zinc Catalyst[J].J. Org. Chem.2020,85,4195−4206.

16.Yang Yi,Yuan-Zhao Hua,(*)Hui-Jie Lu, Lan-Tao Liu, Min-Can Wang.(*)Br➢nsted Base and Lewis Acid Cooperatively Catalyzed Asymmetricexo'‑Selective [3 + 2] Cycloaddition of Trifluoromethylated Azomethine Ylides and Methyleneindolinones[J].Org. Lett.2020,22, 2527–2531.

17.Xiao-Chao Yang, Meng Xu, Jin-Bao Wang, Meng-Meng Liu, François Mathey,Yuan-Zhao Hua,(*)Min-Can Wang.(*)Enantioselective synthesis of indanone spiro-isochromanone derivatives via a dinuclear zinc-catalyzed Michael/transesterification tandemreaction[J].Org. Biomol. Chem.2020,18, 3917–3926.

专利申请:

1.华远照,杨小超,王瑞丽,刘萌萌,耿宇欢,郭亚军,王敏灿。一种手性氮杂半冠醚多齿配体及其制备方法与应用。中国专利,申请号:201910425729.6

2.华远照,杨小超,耿宇欢,刘萌萌,王瑞丽,郭亚军,王敏灿。一种手性3,2’-四氢吡咯双螺氧化吲哚衍生物及其制备方法。中国专利,申请号:201910424305.8

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