杨帆，博士，副教授
E-mail：yangf@zzu.edu.cn
通讯地址：郑州市大学北路75号郑州大学南校区
教育、工作履历
2000.09-2004.06 郑州大学化学学院，化学专业本科
（导师：吴养洁院士）
2004.09-2009.06 郑州大学化学学院，有机化学专业硕博连读
（导师：吴养洁院士）
2009.07-至今 郑州大学化学学院
科研情况
1.科研项目：国家自然科学基金青年项目，苯并杂环衍生物的新合成方法研究，编号：21102134，2012.01-2014.12，主持，已结题
2.研究领域：金属有机化学与有机合成方法学
研究成果（Selected publications）
1. Copper(II)-Catalyzed Direct Amination of 1-Naphthylamines at the C8 Site Zu, Conghui; Zhang, Tingfang; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Journal of Organic Chemistry 2020, 85(19), 12777–12784.
2. Palladium-catalyzed C8-H alkoxycarbonylation of 1-naphthylamines with alkyl chloroformates Shi, Yaqi; Yang, Fan*; Wu, Yangjie* Organic & Biomolecular Chemistry 2020, 18(24), 4628-4637.
3. Merging photoredox catalysis with transition metal catalysis: Direct C4-H amination of 8-hydroxyquinoline derivatives Ma, Yueyue; Shi, Yaqi; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Tetrahedron 2019, 75(29), 3904-3910.
4. Pd(II)-Catalyzed C8-H alkoxycarbonylmethylation of 1-naphthylamides withα-chloroalkyl esters Wang, Xiaolong; Feng, Cancan; Yang, Fan*; Wu, Yangjie* Organic & Biomolecular Chemistry 2019, 17(19), 4865-4868.
5. Palladium-Catalyzed C8-H Acylation of 1-Naphthylamines with Acyl Chlorides Yu, Xiaomeng; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Organic Letters 2019, 21(6), 1726-1729.
6. Cobalt(II)-catalyzed C8-H alkoxylation of 1-naphthylamine derivatives with alcohols Zhang, Tingfang; Zhu, Hongmei; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Tetrahedron 2019, 75(11), 1541-1547.
7. Direct C4-H phosphonation of 8-hydroxyquinoline derivatives employing photoredox catalysis and silver catalysis Su, Xiaoxue; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Organic & Biomolecular Chemistry 2018, 16(15), 2753-2756.
8. Silver(I)-Catalyzed C4-H Amination of 1-Naphthylamine Derivatives with Azodicarboxylates Zhu, Hongmei; Sun, Suyan; Qiao, Huijie; Yang, Fan*; Kang, Jianxun; Wu, Yusheng*; Wu, Yangjie* Organic Letters 2018, 20(3), 620-623.
9. Copper-catalyzed decarboxylative coupling of alkenyl acids with P(O)H compounds at room temperature Qiao, Huijie; Sun, Suyan; Kang, Jianxun; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Youji Huaxue 2018, 38(1), 86-94.
10. Ru/Cu Photoredox or Cu/Ag Catalyzed C4-H Sulfonylation of 1-Naphthylamides at Room Temperature Bai, Peirong; Sun, Suyan; Li, Zexian; Qiao, Huijie; Su, Xiaoxue; Yang, Fan*; Wu, Yusheng*; Wu, Yangjie* Journal of Organic Chemistry 2017, 82(23), 12119-12127.
11. Merging photoredox catalysis with transition metal catalysis: site-selective C4 or C5-H phosphonation of 8-aminoquinoline amides Qiao, Huijie; Sun, Suyan; Zhang, Yue; Zhu, Hongmei; Yu, Xiaomeng; Yang, Fan*; Wu, Yusheng*; Li, Zhongxian; Wu, Yangjie* Organic Chemistry Frontiers2017,4(10),1981-1986.
12. Merging photoredox catalysis with iron(III) catalysis: C5-H bromination and iodination of 8-aminoquinoline amides in water HuijieQiao; Sun, Suyan; Yang, Fan*; Zhu, Yu; Kang, Jianxun; Wu, Yusheng*; Wu, Yangjie* Advanced Synthesis & Catalysis2017, 359(11), 1976-1980.
13. Silver(I)-promoted C5-H phosphonation of 8-aminoquinoline amides with H-phosphonates Sun, Mengmeng; Sun, Suyan; Qiao, Huijie; Yang, Fan*; Zhu, Yu; Kang, Jianxun; Wu, Yusheng*; Wu, Yangjie* Organic Chemistry Frontiers 2016, 3(12), 1646-1650.
14. Palladium-Catalyzed Regioselective C8-H Amination of 1-Naphthylamine Derivatives with Aliphatic Amines Li, Zexian; Sun, Suyan; Qiao, Huijie; Yang, Fan*; Zhu, Yu; Kang, Jianxun; Wu, Yusheng*; Wu, Yangjie* Organic Letters 2016, 18(18), 4594-4597.
15. Palladium-catalyzed direct C-H arylation of ferrocenecarboxamides with aryl halides Qiao, Huijie; Sun, Suyan; Yang, Fan*; Zhu, Yu; Zhu, Weiguo; Wu, Yusheng*; Wu, Yangjie* RSC Advances 2016, 6(64), 59319-59326.
16. Direct Decarboxylative Alkynylation of α,α-Difluoroarylacetic Acids under Transition Metal-Free Conditions Li, Xiang; Li, Siyu; Sun, Suyan; Yang, Fan*; Zhu, Weiguo; Zhu, Yu; Wu, Yusheng*; Wu, Yangjie* Advanced Synthesis & Catalysis 2016, 358(10), 1699-1704.
17. Pd-catalyzed aminocarbonylation of alkynes with amines using Co2(CO)8as a carbonyl source Dong, Yaxi; Sun, Suyan; Yang, Fan*; Zhu, Yu; Zhu, Weiguo; Qiao, Huijie; Wu, Yusheng*; Wu, Yangjie* Organic Chemistry Frontiers 2016, 3(6), 720-724.
18. Copper(I)-Catalyzed Sulfonylation of 8-Aminoquinoline Amides with Sulfonyl Chlorides in Air Qiao, Huijie; Sun, Suyan; Yang, Fan*; Zhu, Yu; Zhu, Weiguo; Dong, Yaxi; Wu, Yusheng*; Kong, Xiangtao; Jiang, Ling; Wu, Yangjie* Organic Letters 2015, 17(24), 6086-6089.
19. Copper-catalyzed direct decarboxylative hydrosulfonylation of arylpropiolic acids with sulfonylhydrazides leading to vinylsulfones Li, Siyu; Li, Xiang; Yang, Fan*; Wu, Yangjie* Organic Chemistry Frontiers 2015, 2(9), 1076-1079.
20. Arylmethyl Chlorides: New Bifunctional Reagents for Palladium-Catalyzed ortho-Chlorination and Acylation of 2-Arylpyridines Zhang, Guodong; Sun, Suyan; Yang, Fan*; Zhang, Qian; Kang, Jianxun; Wu, Yusheng*; Wu, Yangjie* Advanced Synthesis & Catalysis2015,357(2-3),443-450.
21. Palladium-catalyzed oxidative deacetonative coupling of 4-aryl-2-methyl-3-butyn-2-ols with H-phosphonates Li, Xiang; Sun, Suyan; Yang, Fan*; Kang, Jianxun; Wu, Yusheng*; Wu, Yangjie* Organic & Biomolecular Chemistry2015,13(8),2432-2436.
22. Copper-catalyzed synthesis of 2-arylbenzoxazoles from o-aminophenol derivatives with arylmethyl chlorides Zhang, Guodong; Wang, Peng; Yang, Fan*; Wu, Yangjie* Tetrahedron2015,71(1),57-63.
23. One-pot synthesis of unsymmetrical diarylacetylenes via Sonogashira/deacetonation/Sonogashira cross-coupling of two different aryl chlorides with 2-methyl-3-butyn-2-ol Xu, Kai; Sun, Suyan; Zhang, Guodong; Yang, Fan*; Wu, Yangjie* RSC Advances2014,4(62),32643-32646.
24. DDQ: the chlorinating reagent and oxidant for the ligand-directed ortho-chlorination of 2-arylpyridines Zhang, Qian; Yang, Fan*; Wu, Yangjie* Organic Chemistry Frontiers2014,1(6),694-697.
25. Synthesis of diarylalkynes via tandem Sonogashira/decarboxylative reaction of aryl chlorides with propiolic acid Li, Xiang; Yang, Fan*; Wu, Yangjie* RSC Advances2014,4(26),13738-13741.
26. Copper-Mediated Oxidative Decarboxylative Coupling of Arylpropiolic Acids with Dialkyl H-Phosphonates in Water Li, Xiang; Yang, Fan*; Wu, Yangjie; Wu, Yusheng* Organic Letters2014,16(3),992-995.
27. Palladacycle-Catalyzed Deacetonative Sonogashira Coupling of Aryl Propargyl Alcohols with Aryl Chlorides Hu, Hao; Yang, Fan*; Wu, Yangjie* Journal of Organic Chemistry2013,78(20),10506-10511.
28. Palladium-catalyzed ortho-acylation of 2-aryl pyridine derivatives using arylmethyl amines as new acyl sources Zhang, Qian; Yang, Fan*; Wu, Yangjie* Chemical Communications 2013, 49(61), 6837-6839.
29. Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles and 2-arylbenzothiazoles using arylmethyl alcohols as the acyl source Zhang, Qian; Yang, Fan*; Wu, Yangjie* Tetrahedron2013,69(24),4908-4914.
30. Palladacycle-Catalyzed Decarboxylative Coupling of Alkynyl Carboxylic Acids with Aryl Chlorides under Air Li, Xiang; Yang, Fan*; Wu, Yangjie* Journal of Organic Chemistry 2013, 78(9), 4543-4550.
31. Palladacycle-catalyzed phosphonation of aryl halides in neat water Xu, Kai; Yang, Fan*; Zhang, Guodong; Wu, Yangjie* Green Chemistry 2013, 15(4), 1055-1060.
32. Synthesis of Aryl and Arylmethyl Phosphonates by Cross-Coupling of Aryl or Arylmethyl Halides (X = I, Br and Cl) with Diisopropyl H-Phosphonate Xu, Kai; Hu, Hao; Yang, Fan*; Wu, Yangjie* European Journal of Organic Chemistry 2013, (2), 319-325.
33. Palladium-catalyzed ortho-acylation of 2-arylbenzoxazoles Zhang, Qian; Li, Chao; Yang, Fan*; Li, Jingya; Wu, Yangjie* Tetrahedron 2013, 69(1), 320-326.
34. Pd/Cu-catalyzed oxidation of alkynes into 1,2-diketones using DMSO as the oxidant Gao, Ang; Yang, Fan*; Li, Ji; Wu, Yangjie* Tetrahedron2012, 68(25), 4950-4954.
35. Cyclopalladated ferrocenylimine catalyzed chlorination of 2-arylbenzoxazoles Leng, Yuting; Yang, Fan*; Wu, Yangjie*; Li, Ke Chinese Journal of Chemistry2011,29(8),1703-1708.
36. Facile synthesis of indenones by cyclopalladated ferrocenylimine-catalyzed annulation of internal alkynes Zhang, Junli; Yang, Fan*; Wu, Yangjie* Applied Organometallic Chemistry2011,25(9),675-679.
37. Facile synthesis of arylboronic esters by palladacycle-catalyzed bromination of 2-arylbenzoxazoles and subsequent borylation of the brominated products Leng, Yuting; Yang, Fan*; Zhu, Weiguo; Zou, Dapeng; Wu, Yangjie*; Cai, Ranran Tetrahedron2011,67(34),6191-6196.
38. Chlorination and ortho-acetoxylation of 2-arylbenzoxazoles Leng, Yuting; Yang, Fan*; Zhu, Weiguo; Wu, Yangjie*; Li, Xiang Organic & Biomolecular Chemistry2011,9(14),5288-5296.
39. Facile synthesis of isoquinolines by imination and subsequent palladacycle-catalyzed iminoannulation of internal alkynes Yang, Fan; Zhang, Junli; Wu, Yangjie* Tetrahedron2011,67(16), 2969-2973.
40. Cyclopalladated ferrocenylimines as efficient catalysts for homogeneous catalysis. A brief introduction to our preliminary achievements Wu, Yangjie*; Yang, Fan; Zhang, Jinli; Cui, Xiuling; Gong, Junfang; Song, Maoping; Li, Tiesheng Chinese Science Bulletin 2010, 55(25), 2784-2793.
41. Generally applicable and efficient oxidative Heck reaction of arylboronic acids with olefins catalyzed by cyclopalladated ferrocenylimine under base- and ligand-free conditions Leng, Yuting; Yang, Fan*; Wei, Kun; Wu, Yangjie* Tetrahedron2010,66(6),1244-1248.
42. Modified palladium-catalyzed regioselective ortho-arylation of sp2 C-H bond substrates with a low catalyst loading Yang, Fan; Wu, Yangjie*; Li, Yanan; Wang, Biao; Zhang, Junli Tetrahedron2009,65(4),914-919.
43. Cyclopalladated ferrocenylimine catalyzed ortho-arylation of sp2 C-H bond substrates containing the directing group Li, Ya-Nan; Yang, Fan*; Wu, Yang-Jie* Gaodeng Xuexiao Huaxue Xuebao2008,29(12),2535-2541.
44. Direct ortho-arylation of 2-arylbenzoxazoles via C-H activation Yang, Fan; Wu, Yangjie*; Zhu, Zhiwu; Zhang, Junli; Li, Yanan Tetrahedron2008,64(28), 6782-6787.
45. Facile synthesis of substituted alkynes by cyclopalladated ferrocenylimine catalyzed cross-coupling of arylboronic acids/esters with terminal alkynes Yang, Fan; Wu, Yangjie* European Journal of Organic Chemistry2007,(21),3476-3479.
46. Cyclopalladated ferrocenylimines: efficient catalysts for homocoupling and Sonogashira reaction of terminal alkynes Yang, Fan; Cui, Xiuling; Li, Yanan; Zhang, Jinli; Ren, Gerui; Wu, Yangjie* Tetrahedron 2007, 63(9), 1963-1969.
奖励与荣誉
1. 金属有机化合物在催化偶联与制备发光材料中的应用,国家教育部,高等学校自然科学二等奖,第六名, 2014.
2. 河南省优秀硕士论文指导教师, 2018.
