李二庆

作者: 时间:2018-03-14 点击数:

李二庆,博士,校聘副教授,硕士生导师

   话:15038289596

E-mail: lierqing@zzu.edu.cn

通讯地址:郑州大学化学学院

课题组网站:www.x-mol.com/groups/duanzheng

*        教育背景

2010-2015年 南开大学 博士(导师:黄有 教授)

2006-2010年 河南师范大学 学士

*        工作履历

2016.11-至今 郑州大学 化学与分子工程学院 讲师(校聘副教授)

2015-2016年 德国哥廷根大学 博士后(adviser: Prof. Lutz F. Tietze)

 

*         研究领域

过渡金属催化的不对称催化反应

新型磷手性中心手性膦配体的设计合成

有机磷化学

*        科研项目

国家自然科学基金青年项目,21702189,在研,主持;

中国博士后科学基金第十一批特别资助项目,2018T110737,在研,主持;

中国博士后科学基金第61批面上一等资助项目,2017M610458,在研,主持

*        学术成果

1. Phosphine-catalyzed regiodivergent annulations of γ-substituted allenoates with conjugated dienes. Zhenjie Gan, Yanchuan Gong, Yunpeng Chu, Er-Qing Li,* You Huang* and Zheng Duan* Chem. Commun., 2019, DOI: 10.1039/c9cc05207k.

2. Ag/P-Stereogenic Phosphine-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions: A Method to Optically Active Pyrrolidines Zhi Mengna, Gan Zhenjie, Ma Rong, Cui Hao, Li Er-Qing,* Duan Zheng,* and Mathey François Org. Lett. 2019, 21, 3210-3213.

3. P-Stereogenic Phosphines Directed Copper(I)-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions Gan Zhenjie, Zhi Mengna, Han Ruiping, Li Er-Qing ,* Duan Zheng,* and Mathey François Org. Lett., 2019, 21, 2782–2785.

4. Enantiand Diastereoselective Synthesis of βArylβpyrazolyl αAmino Acid Esters via CopperCatalyzed Reaction of Azomethine Ylides with Benzylidenepyrazolones Gong Yan-Chuan, Wang Yue, Li Er-Qing,* Cui Hao, Duan Zheng * Adv. Synth. Catal. 2019, 361, 1389-1393.

5. Qiu-Zhen Xi, Zhen-Jie Gan, Er-Qing Li,*and Zheng Duan* Brønsted Acid Tuned, Lewis Base Promoted [4 + 2] Annulation Reactions of Allenoates with Electron-Deficient Olefins. Eur. J. Org. Chem. 2018, 4917-4925.

6. Bifunctional-Phosphine-Catalyzed Sequential Annulations of Allenoates and Ketimines: Construction of Functionalized Poly-heterocycle Rings. Erqing Li, Hongxing Jin, Penghao Jia, Xuelin Dong, You Huang* Angew. Chem. Int. Ed. 2016, 55(38), 11591-11594.

7. Phosphine-Catalyzed Sequential [2 +3] and [3 + 2] Annulation Domino Reaction of γ- Benzyl Substituted Allenoates with α,β-Unsaturated Ketimines To Construct Aza-bicyclo[3, 3, 0]octane Derivatives Erqing Li, Penghao Jia, Ling Liang, You Huang* ACS Catal. 2014, 4, 600−603.

8. Phosphine-Catalyzed [4+2] Annulation of gamma-Substituent Allenoates: Facile Access to Functionalized Spirocyclic Skeletons. Erqing Li, You Huang,* Ling Liang, Peizhong Xie Org. Lett. 2013, 15, 3138-3141.

9. Divergent Phosphine Catalyzed [2 + 4] or [3 + 2] Cycloaddition Reactions of γ- Substituted Allenoates with Oxo-dienes. Erqing Li, Meijia Chang, Ling Liang and You Huang* Eur. J. Org. Chem. 2015, 710-714.

10. Phosphine-catalyzed Domino Reaction: A Novel Sequential [2+3] and [3+2] Annulation Reaction of γ-Substituent Allenoates to Construct Bicyclic[3, 3, 0]octene Derivatives. Erqing Li, You Huang* Chem. Commun., 2014, 50, 948-950.

11. Phosphine-Catalyzed Domino Reaction: A Novel Method Access to Functionalized Bicyclic Skeletons Erqing Li, You Huang* Chem. Eur. J., 2014, 20, 3520.

12. Tuning Catalysts to Tune the Products: Phosphine-Catalyzed Aza-Michael Addition Reaction of Hydrazones with Allenoates


*   奖励与荣誉

2014年博士生国家奖学金

2013年南开大学一等奖学金

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