李保军,男,1980年10月生,理学博士(博士后),科研型教授,高级工程师,博士生导师,郑州大学学科振兴行动计划青年学术带头人。
教育/工作经历
1. 1998年9月至2002年7月,郑州大学,化学与化工学院,本科/学士,化学;
2. 2002年9月至2005年7月,郑州大学,化学系,研究生/硕士,物理化学;
3. 2006年9月至2009年8月,南京大学,化学与化工学院,研究生/博士,无机化学;
4. 2009年9月至2011年8月,清华大学,化学系,博士后出站;
5. 2011年8月至今,郑州大学,化学与分子工程学院,物理化学专业,研究教学工作。
联系方式
办公电话:0371-67781064;18236992415
邮箱:lbjfcl@zzu.edu.cn
研究方向
面向能源和环境问题,以催化、储能、吸附分离功能为导向,在原子-分子水平上精确调控凝聚态物质结构,监控和揭示纳米体系表面动态变化,为理性设计具有特殊结构-性质-性能关系的材料和过程提供基础。基于富勒烯、碳纳米管、石墨烯、氮化碳、MXene等新型碳结构和过渡金属化合物低维异质结构,构建非贵金属碳基复合材料,控制合成微孔分子筛纳米/微米晶或介晶组装体,用作固体催化剂。近期,着重氢能源和电化学储能相关石墨烯基复合材料、生物质资源转化关键催化材料和过程强化研究。
承担项目
1. 2017年至2019年:主持企业委托开发项目(非贵金属电解水催化剂开发,No. 20170283A,100万,进行中)。
2. 2017年至2020年:主持企业委托开发项目(钴-碳基复合材料开发,No. 20170287A,30万,进行中)。
3. 2015年至2017年:主持中国国家自然科学基金青年科学基金项目(在石墨烯上合成金属有机骨架化合物用作热解前驱体构建复合电极材料,No. 21401168,25万,进行中)。
4. 2015年至2017年:主持郑州大学优秀青年教师发展基金项目(在石墨烯上合成金属有机骨架化合物用作热解前驱体构建复合电极材料,No. 1421316037,30万,进行中)。
5. 2013年至2015年:主持郑州大学学科振兴行动计划资助项目(石墨烯基三维有序复合材料构建及性能研究,30万,已结项)。
6. 2010年至2011年:主持中国博士后科学基金项目(富勒烯-半导体复合催化剂的制备、表征及光催化性能研究,No. 20100470302,3万,已结项)。
7. 2012年至2013年:主持中国博士后科学基金项目(石墨烯辅助微孔分子筛形貌可控合成及其催化性能,No. 2012M511121,5万,已结项)。
8. 2013年至2014年:主持中国博士后科学基金项目(石墨烯辅助MOFs形貌可控合成及吸附性能研究,No. 2013T60705,15万,已结项)。
研究成果
1. 取得了系统的高水平研究成果。在SCI收录国际杂志发表英文论文共66篇。其中发表在化学一级学科顶级期刊论文5篇(美国《Journal of the American Chemical Society》1篇,英国《Chemical Communications》4篇),发表在材料化学、无机化学、物理化学二级学科一流期刊论文61篇。发表第一作者或通讯作者论文38篇。
2. 发表在美国《Inorganic Chemistry》二级学科一流期刊论文1篇,被该杂志选为封面介绍论文。
3. 发表在英国《Journal of Materials Chemistry A》二级学科一流期刊论文1篇,被该杂志选为封底介绍论文。
4. 被英国《Journal of Materials Chemistry》杂志评价为当月阅读量Top ten的论文2篇。
5. 被中国科学技术信息研究所评为2011年中国百篇最具影响力国际学术论文2篇。
6. 所发表论文被国际著名期刊正面引用多次,2018年2月20日通过Web of knowledge检索,被正面他引2260次,总引2520次,H-index达到25,被引用超过300、200、100、50次论文分别1、3、5、11篇,近6年来每年被引300次以上,并逐年递增。
7. 共申请中国发明专利16项。
近期主要论文
1. Baojun Li and Zheng Xu*, A Nonmetal Catalyst for Molecular Hydrogen Activation with Comparable Catalytic Hydrogenation Capability to Noble Metal Catalyst. Journal of the American Chemical Society 2009, 131 (45), 16380–16382.
2. Baojun Li, Man Ai and Zheng Xu*, Mesoporous β-Ni(OH)2: Synthesis and Enhanced Electrochemical Performance. Chemical Communications 2010, 46 (34), 6267–6269.
3. Baojun Li, Huaqiang Cao*, Jin Shao, He Zheng and Meizhen Qu, Improved Performances of β-Ni(OH)2@reduced-graphene-oxide in Ni-MH and Li-ion Batteries. Chemical Communications 2011, 47 (11), 3159–3161.
4. Baojun Li, Huaqiang Cao*, Jin Shao and Meizhen Qu, Enhanced Anode Performances of Fe3O4-Carbon-rGO Three Dimensional Composite in Lithium Ion Batteries. Chemical Communications 2011, 47 (37), 10374–10376.
5. Baojun Li, Huaqiang Cao*, Jin Shao, Guoqiang Li, Meizhen Qu* and Gui Yin, Co3O4@graphene Composites as Anode Materials for High-performance Lithium-ion Batteries. Inorganic Chemistry 2011, 50 (5), 1628–1632.
6. Baojun Li and Huaqiang Cao*, ZnO@graphene Composite with Enhanced Performance in Removal of Dye from Water. Journal of Materials Chemistry 2011, 21 (10), 3346–3349.
7. Baojun Li, Huaqiang Cao*, Jin Shao, Meizhen Qu, and Jamie H. Warner, Superparamagnetic Fe3O4 Nanocrystals@Graphene Composites for Energy Storage Devices. Journal of Materials Chemistry 2011, 21 (13), 5069–5075.
8. Baojun Li, Huaqiang Cao*, Gui Yin, Yuexiang Lu, and Jiefu Yin, Cu2O@reduced Graphene Oxide Composite for Removal of Contaminants from Water and Supercapacitor. Journal of Materials Chemistry 2011, 21 (29), 10645–10648.
9. Baojun Li, Huaqiang Cao* and Gui Yin, Mg(OH)2@Reduced Graphene Oxide Composite for Removal of Dyes from Water. Journal of Materials Chemistry 2011, 21 (36), 13765–13768.
10. Baojun Li, Huaqiang Cao*, Jiefu Yin, Yimin A. Wu and Jamie H. Warner, Synthesis and Separation of Dyes via Ni@reduced Graphene Oxide Nanostructures. Journal of Materials Chemistry 2012, 22 (5), 1876–1883.
11. Baojun Li, Huaqiang Cao*, Jingxian Zhang, Meizhen Qu, Fang Lian and Xianghua Kong, SnO2–carbon–RGO Heterogeneous Electrode Materials with Enhanced Anode Performances in Lithium Ion Batteries. Journal of Materials Chemistry 2012, 22 (7), 2851–2854.
12. Huaqiang Cao,* Baojun Li, Jingxian Zhang, Fang Lian, Xianghua Kong and Meizhen Qu, Synthesis and superior anode performance of TiO2@reduced graphene oxide nanocomposites for lithium ion batteries. Journal of Materials Chemistry 2012, 22, 9759–9766.
13. Baojun Li, Hongbian Li and Zheng Xu*, Experimental Evidence for the Interface Interaction in Ag/C60 Nano Composite Catalyst and Its Crucial Influence on Catalytic Performance. The Journal of Physical Chemistry C 2009, 113 (52), 21526–21530.
以上论文为求学期间发表。
14. Huijuan Wei, Hongbian Li, Yangqing Liu, Peng Jin, Xiangyu Wang* and Baojun Li*, Oxidation-Resistant Acidic Resins Prepared by Partial Carbonization as Cocatalysts in Synthesis of Adipic Acid. ACS Appl. Mater. Interfaces 2012, 4 (8), 4106−4112.
15. Yiqiang Wen, Xiangyu Wang*, Huijuan Wei, Baojun Li*, Peng Jin and Limin Li, A large-scale continuous-flow process for the production of adipic acid via catalytic oxidation of cyclohexene with H2O2. Green Chem. 2012, 14, 2868–2875.
16. Yameng Ren, Juan Zhang, Yanyan Liu, Hongbian Li, Huijuan Wei, Baojun Li* and Xiangyu Wang*, Synthesis and Superior Anode Performances of TiO2-Carbon-rGO Composites in Lithium Ion Batteries. ACS Appl. Mater. Interfaces 2012, 4, 4776–4780.
17. Changming Ye, Peng Jin, Junxia Liu, Yiqiang Wen, Huijuan Wei, Xiaoguang Zheng*, Xiangyu Wang* and Baojun Li*, Process for Recycling Tungsten from the Leach Solution of Organic Oxidation Reaction Systems. Ind. Eng. Chem. Res. 2013, 52 (10), 3600–3606.
18. Huijuan Wei, Tian Zhao, Yangqing Liu, Guanghe Li, Xiangyu Wang* and Baojun Li*, Synthesis of TS-1 Submicrocrystals from Inorganic Reactants by a Seed Method for the Vapor Beckmann Rearrangement of Cyclohexanone Oxime. RSC Adv. 2013, 3 (43), 20811–20815.
19. Sankui Xu, Peng Zhang, Hongbian Li, Huijuan Wei, Limin Li,* Baojun Li* and Xiangyu Wang, Ru Nanoparticles Confined in Carbon Nanotubes: Supercritical CO2 Assisted Preparation and Improved Catalytic Performances in Hydrogenation of D-glucose. RSC Adv. 2014, 4 (14), 7079–7083.
20. Dan Kong, Yanyan Liu, Juan Zhang, Hongbian Li, Xiangyu Wang*, Guangyu Liu, Baojun Li* and Zheng Xu, Hierarchically Porous AlPO-5-based Microspheres as Heterogeneous Catalysts for Synthesis of 5-Substituted 1H-Tetrazoles via [3+2] Cycloaddition. New J. Chem., 2014, 38 (7), 3078–3083.
21. Yan Xue, Yunlong Xie, Huijuan Wei, Yiqiang Wen, Xiangyu Wang* and Baojun Li*, Improving the performance of TS-1 catalyst for continuous cyclohexanone ammoximation through controlment of active species distribution. New J. Chem., 2014, 38 (9), 4229–4234.
22. Huijuan Wei, Ning Zhang, Tian Zhao, Yangqing Liu, Yiqiang Wen, Xiangyu Wang* and Baojun Li*, Controlling Microstructure of MFI Zeolites with Mg(OH)2 Nanocrystals to Improve Their Catalytic Performances. RSC Adv., 2015, 5 (5), 3642–3647.
23. Hang Du, Zhen Wang, Yanyan Liu, Yinghao Chen, Yushan Liu, Baojun Li*, Xiangyu Wang* and Huaqiang Cao, Anchoring superparamagnetic core-shells onto reduced graphene oxide: fabrication of Ni-carbon-rGO nanocomposite for effective adsorption and separation. RSC Adv., 2015, 5 (13), 10033–10039.
24. Yan Xue, Yiqiang Wen, Huijuan Wei, Meng Liu, Xiaoyan Huang, Xiaoxue Ye, Xiangyu Wang* and Baojun Li*, Hollow TS-1 mesocrystals: hydrothermal construction and high catalytic performances in cyclohexanone ammoximation. RSC Adv., 2015, 5 (64), 51563–51569.
25. Yuanchao Li, Jinghao Hao, Guangwei Geng, Yafang Wang, Xiaokun Shang, Changchun Yang* and Baojun Li*, Large-scale preparation of Mg doped LiFePO4@C for lithium ion batteries via carbon thermal reduction combined with aqueous rheological phase technology. RSC Adv., 2015, 5 (84), 68681–68687.
26. Yuanchao Li, Guangwei Geng, Jinghao Hao, Jianmin Zhang, Changchun Yang* and Baojun Li*, Optimized synthesis of LiFePO4 composites via rheological phase assisted method from FePO4 with acetic acid as dispersant. Electrochimica Acta, 2015, 186, 157–164.
27. Xiujun Zhang, Juan Zhang, Yanyan Liu, Xiangyu Wang and Baojun Li*, Improving the anode performances of TiO2–carbon–rGO composites in lithium ion batteries by UV irradiation. New J. Chem., 2015, 39 (12), 9345–9350.
28. Yanyan Liu, Juan Zhang, Xiujun Zhang, Baojun Li*, Xiangyu Wang, Huaqiang Cao, Di Wei, Zhongfu Zhou and Tony Cheetham, Magnetic catalysts as nanoactuator achieve simultaneously momentum-transfer and continuous-flow hydrogen production. J. Mater. Chem. A, 2016, 4 (11), 4280–4287.
29. Shasha Duan, Guosheng Han, Yongheng Su, Xiaoyu Zhang, Yanyan Liu, Xianli Wu* and Baojun Li*, Magnetic Co@g-C3N4 Core-Shells on rGO Sheets for Momentum Transfer with Catalytic Activity toward Continuous-Flow Hydrogen Generation. Langmuir, 2016, 32 (25), 6272–6281.
30. Congcong Xing, Yanyan Liu, Yongheng Su, Yinghao Chen, Shuo Hao, Xianli Wu, Xiangyu Wang, Huaqiang Cao and Baojun Li*, Structural Evolution of Co-Based Metal Organic Frameworks in Pyrolysis for Synthesis of Core–Shells on Nanosheets: Co@CoOx@Carbon-rGO Composites for Enhanced Hydrogen Generation Activity. ACS Appl. Mater. Interfaces, 2016, 8 (24), 15430–15438.
31. Yuanchao Li, Jinghao Hao, Fengli Wei, Lei Fu, Yu Liu, Zhongju Wang, Changchun Yang* and Baojun Li*, Synthesis of Mg-LiFePO4/C composite using intermediate FePO4×2H2O from Fe3(PO4)2×8H2O as precursor via anaqueous rheological phase assisted method. Journal of Materials Science: Materials in Electronics, 2016, 27 (9), 9398–9404.
32. Yanyan Liu, Shimin Wang, Congcong Xing, Hang Du, Chenxia Du* and Baojun Li*, Nanoporous Carbon Derived from Core−Shells@Sheets through the Template-Activation Method for Effective Adsorption of Dyes. ACS Omega, 2016, 1 (3), 491–497.
33. Zhikun Peng, Xu Liu, Huinan Lin, Zhuo Wang, Zhongjun Li, Baojun Li*, Zhongyi Liu* and Shouchang Liu, Surface engineering on a nanocatalyst: basic zinc salt nanoclusters improve catalytic performances of Ru nanoparticles. J. Mater. Chem. A, 2016, 4 (45), 17694–17703.
34. Zhikun Peng, Xu Liu, Shuaihui Li, Zhongjun Li, Baojun Li*, Zhongyi Liu* and Shouchang Liu, Heterophase-structured nanocrystals as superior supports for Ru-based catalysts in selective hydrogenation of benzene. Scientific Reports, 2017, 7, Article number: 39847, doi: 10.1038/srep39847.
35. Zhikun Peng, Xu Liu, Huan Meng, Zhongjun Li, Baojun Li*, Zhongyi Liu* and Shouchang Liu, Design and Tailoring of the 3D Macroporous Hydrous RuO2 Hierarchical Architectures with a Hard-Template Method for High-Performance Supercapacitors. ACS Appl. Mater. Interfaces, 2017, 9 (5), 4577–4586.
36. Yanyan Liu, Guosheng Han, Xiaoyu Zhang, Congcong Xing, Chenxia Du,* Huaqiang Cao, and Baojun Li,* Co-Co3O4@carbon core-shells derived from metal−organic framework nanocrystals as efficient catalyst for hydrogen evolution. Nano Research, 2017, 10 (9), 3035–3048.
37. Jiao Zhang, Jinghao Hao, Qianli Ma, Chuanqi Li, Yushan Liu, Baojun Li,* and Zhongyi Liu,* Polyvinylpyrrolidone stabilized-Ru nanoclusters loaded onto reduced graphene oxide as high active catalyst for hydrogen evolution. J. Nanopart. Res., 2017, 19: 227.
38. Xinwen Zhang,# Yanyan Liu,# Jie Gao, Guosheng Han, Meifang Hu, Xianli Wu,* Huaqiang Cao, Xiangyu Wang, and Baojun Li,* Defect-rich (Co-CoS2)x@Co9S8 Nanosheets Derived from Monomolecular Precursor Pyrolysis with Excellent Catalytic Activity for Hydrogen Evolution Reaction. J. Mater. Chem. A, 2018, DOI: 10.1039/C8TA01163J.
以上论文为独立开展科研工作期间发表。