李二庆，副教授，硕士生导师，郑州大学青年拔尖人才
邮箱：lierqing@zzu.edu.cn
电话：15038289596
工作经历：
2020.06-至今 郑州大学化学学院 副教授，郑州大学青年拔尖人才
2016.11-2020.06 郑州大学化学学院 讲师（校聘副教授）
2015.08-2016.08 德国哥廷根大学 博士后（adviser：Prof. Lutz F. Tietze）
学习经历：
2010.09-2015.06 南开大学元素有机国家重点实验室 博士 导师：黄有教授
2006.09-2010.06 河南师范大学化学与化工学院 学士
研究方向：有机合成方法学，不对称催化，手性磷配体的设计合成，有机膦化学
主持项目
1.国家自然科学基金青年基金项目：磷手性中心配体的设计、合成及在不对称催化领域的应用（基金号21702189），2018-2020 主持
2.第11批中国博士后科学基金特别资助：新型1-磷杂降冰片二烯类手性配体参与的不对称反应研究（基金号2018T110737）主持
3.第61批中国博士后基金面上项目一等资助：手性膦催化剂的设计、合成及应用研究（基金号：2017M610458）主持
4.河南省科技攻关项目：螺环羟吲哚化合物高立体选择性的合成及其活性研究（基金号：202102310004）主持
5.河南省博士后科研项目一等资助：磷手性中心配体的设计合成及应用研究（基金号001701006）主持
发表论文
1.Erqing Li, Hongxing Jin, Penghao Jia, Xuelin Dong, You Huang* Bifunctional-Phosphine- Catalyzed Sequential Annulations of Allenoates and Ketimines: Construction of Functionalized Poly-heterocycle Rings.Angew. Chem. Int. Ed.2016,55, 11591 –11594.
2. Lulu Wu, Bing Yu,*Er-Qing Li,* Recent Advances in Organocatalyst‐Mediated Benzannulation Reactions.Adv. Synth. Catal.,2020,362, 4010-4126.
Lulu Wu, Kaihong Chen,* You Huang,*Er-Qing Li,* Phosphine‐Catalyzed δ‐Addition Reaction of γ‐Substituted Allenoates with Isatin Derivatives.Asian J. Org. Chem., 2020,9, 1179-1182.
3.Er-Qing Li, You Huang,* Recent advances in phosphine catalysis involving γ-substituted allenoates.Chem. Commun.,2020,56, 680-694
4. Ruiping Han, Yue Ding, Xueke Jin,Er-Qing Li,* Silver/palladium relay catalyzed 1,3-dipole annulation/allylation reactions to access fully substitutedallyl imidazolidines.Org. Biomol. Chem. 2020,18, 646-649
5. Hao Cui, Ke Li, Yue Wang, Manman Song, Congcong Wang, Donghui Wei,*Er-Qing Li,* Zheng Duan* and Francois Mathey, Copper(I)/Ganphos Catalysis: Enantioselective Synthesis of Diversified Spirooxindoles Using Alkyl Substituted Imino Ester and Methyleneindolinones.Org. Biomol. Chem.,2020,18, 3740-3746.
6. Yue Wang, Siming Jia,Er-Qing Li,* Zheng Duan,* Phosphine/Palladium Cooperative Catalysis: (4 + 3) Annulations of Morita–Baylis–Hillman Carbonates and Vinyl Benzoxazinanones.J. Org. Chem.2019,84, 15323-15330.
7. Zhenjie Gan, Yanchuan Gong, Yunpeng Chu,Er-Qing Li,* You Huang* and Zheng Duan* Phosphine-catalyzed regiodivergent annulations of γ-substituted allenoates with conjugated dienes.Chem. Commun.,2019,55, 10120 - 10123.
8. Mengna Zhi, Zhenjie Gan, Rong Ma, Hao Cui,Er-Qing Li,*Zheng Duan,* François Mathey Ag/P-Stereogenic Phosphine-Catalyzed Enantioselective 1,3-Dipolar Cycloadditions: A Method to Optically Active Pyrrolidines.Org. Lett.2019,21, 3210-3213.
9. Zhenjie Gan, Mengna Zhi, Ruiping Han,Er-Qing Li,*Zheng Duan,* and François Mathey P-Stereogenic Phosphines Directed Copper(I)-Catalyzed Enantioselective 1,3-Dipolar CycloadditionsOrg. Lett.,2019,21, 2782–2785.
10. Yan-Chuan Gong, Yue Wang,Er-Qing Li,* Hao Cui, Zheng Duan* Enanti‐and Diastereoselective Synthesis of β‐Aryl‐β‐pyrazolyl α‐Amino Acid Esters via Copper‐Catalyzed Reaction of Azomethine Ylides with BenzylidenepyrazolonesAdv. Synth. Catal.2019,361, 1389-1393.
11.马蓉, 宋格格,奚秋贞,杨柳,李二庆*,段征*有机磷催化γ-甲基联烯酸酯[3 + 2]环化反应有机化学,2019, 39, 2196-2202.
12. Qiu-Zhen Xi, Zhen-Jie Gan,Er-Qing Li,* Zheng Duan* Br➢nsted Acid Tuned, Lewis Base Promoted [4 + 2] Annulation Reactions of Allenoates with Electron-Deficient Olefins.Eur. J. Org. Chem.2018,2018, 4917-4925.
13.Erqing Li, Hongxing Jin, You Huang* Phosphine‐Catalyzed [3 + 2] Annulation of γ‐Substituted Allenoates: Novel Access to Functionalized Cyclopentenes and Bicyclic[3, 3, 0]octene Derivatives.ChemistrySelect2018,3, 12007-12010.
14.Erqing Li, Meijia Chang, Ling Liang, You Huang* Divergent Phosphine Catalyzed [2 + 4] or [3 + 2] Cycloaddition Reactions of γ- Substituted Allenoates with Oxo-dienes.Eur. J. Org. Chem.2015, 710-714.
15.Erqing Li,You Huang,* Phosphine-catalyzed Domino Reaction: A Novel Sequential [2+3] and [3+2] Annulation Reaction of γ-Substituent Allenoates to Construct Bicyclic[3, 3, 0]octene Derivatives.Chem. Commun.,2014,50, 948-950.
16.Erqing Li,You Huang,* Phosphine-Catalyzed Domino Reaction: A Novel Method Access to Functionalized Bicyclic Skeletons.Chem. Eur. J.,2014,20, 3520。
17.Erqing Li,Penghao Jia, Ling Liang, You Huang,* Phosphine-Catalyzed Sequential [2 +3] and [3 + 2] Annulation Domino Reaction of γ- Benzyl Substituted Allenoates with α,β-Unsaturated Ketimines To Construct Aza-bicyclo[3, 3, 0]octane Derivatives.ACS Catal.2014,4, 600-603.
18.Erqing Li,You Huang,* Ling Liang, Peizhong Xie, Phosphine-Catalyzed [4+2] Annulation of gamma-Substituent Allenoates: Facile Access to Functionalized Spirocyclic Skeletons.Org. Lett.2013,15, 3138-3141.
19.Erqing Li,Peizhong Xie, Lihua Yang, Ling Liang, You Huang* Tuning Catalysts to Tune the Products: Phosphine-Catalyzed Aza-Michael Addition Reaction of Hydrazones with Allenoates.Chem. Asian J.2013,8, 603-610.
授权专利：
段征，李二庆，支梦那，甘贞洁手性1-磷杂降冰片二烯衍生物及其合成方法，专利号：ZL201811293427.X
