李恺

作者: 时间:2021-01-14 点击数:

基本信息:

姓名:李恺

学历:博士

职称:副教授

电子邮箱:likai@zzu.edu.cn

电话:0371-67780037

教育经历:

2004.8-2008.7,清华大学化学系学习,获得理学学士学位。

2009.8-2014.7,清华大学化学系学习,获得理学博士学位。导师:童爱军教授

2012.7-2012.9,香港科技大学,交换生。导师:唐本忠院士

2017.3-2017.9,香港科技大学,访问学者。

 

工作经历:

2008.8-2009.7,青海大学应用化学系支教(团中央扶贫接力计划-清华大学第十届研究生支教团项目)

2014.7-今,郑州大学化学学院工作

2019.9起担任郑州大学国家级化学实验教学示范中心副主任

 

研究方向:

聚集诱导发光材料;货币金属团簇;光致变色材料

主持项目:

1. 国家自然科学基金河南联合基金——基于聚集诱导发光(AIE)分子的新型有机光响应荧光材料,项目号U1904172,经费48万元。

2. 国家自然科学基金青年基金——基于螺内酰肼水杨醛希夫碱金属配合物的新型光响应体系,项目号21501150,经费25万元。

3. 河南省自然科学基金优秀青年基金——具有聚集诱导发光(AIE)性能的刺激响应型货币金属团簇,经费25万元。

4. 横向项目——六氟磷酸锂工艺研究,经费10万元。

5. 郑州大学优秀青年教师发展基金——基于水杨醛希夫结构碱的多功能金属有机框架(MOFs),项目号1521316015,经费30万元。

6. 国家粮食局粮油食品工程技术研究中心开放课题项目——新型聚集诱导发光荧光探针及其在油脂酸价检测中的应用,项目号PL2017006,经费3.5万元。

7. 广西有色金属及特色材料加工重点实验室开放基金——以聚集诱导发光配体构筑的稀土金属有机框架材料及其发光行为的研究,项目号2019GXYSOF12,经费5万元。

8. 郑州大学教学改革研究与实践重点项目——以“聚集诱导发光(AIE)”理论为载体开展课程思政建设的研究与实践,经费2万元。

9. 2020年度大学生创新创业训练计划项目重点项目——新型聚集诱导发光材料的发开,项目号202010459003,经费2万元。

获奖:

1. 2020郑州大学优秀班主任

2. 2019-2020学年“郑州大学青年五四奖章”

3. 2019-2020学年郑州大学“三育人”先进个人

4. 2019年郑州大学中青年教师讲课大赛一等奖(示范课)

5. 2019年河南省教学技能竞赛(理科组)二等奖

6. 2019全国大学生创新实验大赛二等奖(指导教师)

7. 郑州大学2018秋季学期网评优秀教师

8. 郑州大学2017-2019年度优秀共产党员

第一作者或通讯作者发表论文:

2020

1. Kong, Y.; Yan, Z.; Li, S.; Su, H.;Li, K.*; Zheng Y.; Zang, S.*,Photo-responsive propeller-like chiral AIE Cu(I) clusters.Angew. Chem. Int. Ed.2020, 53, 5336-5340.

2. Xing, C.; Liu, J.; Chen, F.; Li, Y.*; Lv, C.; Peng, Q.;Hou, H.*;Li, K.*, Diphenyl-1-pyrenylphosphine: Photo-triggered AIE/ACQ transition with remarkable third-order nonlinear optical signal change.Chem. Commun.2020,56, 4220-4223.

3. Peng, Q.; Yang, L.; Li, Y.; Zhang, Y.; Li, T.; Qin, Y.; Song, Y.; Hou, H.*; Li, K.*, Aggregation/viscosity-induced emission and third-order nonlinear optical signal inversion in a TICT system.J. Phys. Chem. C2020,124, 22684-22691.

4. Zhang, M.;Li, K.*; Zang, S.*,Progress in atomically precise coinage metal clusters with AIE and CPL.Adv. Opt. Mater.2020,8, 1902152.

5. Xing, C.; Liu, J.; Yang, L.; Shao, Z.; Xu, W.; Zhao, Y.;Li, K.*; Song, Y.; Hou, H.*, Third-order nonlinear optical adjusting behavior in azobenzene metal complexes.Sci. China Mater.2020, DOI: 10.1007/s40843-020-1429-9.

6. Liu, Y.; Peng, Q.; Li, Y.; Hou, H.*;Li, K.*, A simple strategy for constructing acylhydrazone photochromic system with visible color/emission change and its application in photo-patterning,Chin. Chem. Lett.2020, DOI:10.1016/j.cclet.2020.05.007.

7. Sun, K.; Zhang, Y.; Chen, X.*; Su, H.; Peng, Q.; Yu, B.*; Qu, L.;Li, K.*,A kind of atypical AIEgens used for onephoton/two-photon targeted-imaging in live cells,ACS Appl. Bio Mater.2020,3, 505-511.

8. Li, Y.; Feng, Z.; Li, Y.; Jin, W.; Peng, Q.; Zhang, P.*;Li, K.*,Metal ions-triggered photo-induced fluorescence change in rhodamine B-based photo-responsive complexes,Spectrochim. Acta A2020,230, 118069.

9. 汪婷,张宗培,何占航*,李恺*.无机化学课程教学中一元酸碱溶液pH的定量计算问题.大学化学,2020,35, 129-134.

10. 李恺,何占航,臧双全*,张宗培*.利用聚集诱导发光现象观察分子定向运动的综合实验.化学教育,2020.

11. 李媛媛,何娟,李恺*.材料化学课程线上教学初探.大学化学,2020, 35, 61-65.

12. 李恺*,卢会杰,李媛媛,臧双全,唐本忠*.利用Reimer-Tiemann反应合成水杨醛缩肼聚集诱导发光分子的综合实验.大学化学,2020,35, 53-58.

 

2019

1. Wu, X.; Wei, Z.; Yan, B.; Huang, R.; Liu, Y.;Li, K.*; Zang, S.*; Mak, T. C. W., Mesoporous crystalline silver chalcogenolate cluster assembled-material with tailored photo-luminescence properties.CCS Chem.2019,1, 553-560.

2. Wu, X. H.; Luo, P.; Wei, Z.; Liu, Y. Y.; Huang, R. W.; Dong, X. Y.;Li, K.*; Zang, S. Q.*; Tang, B. Z.*, Guest-triggered aggregation-induced emission in silver chalcogenolate cluster metal-organic frameworks.Adv. Sci.2019,6, 1801304.

3. Sun, K.; Chen, X.*; Zhang, Y.;Li, K.*; Huang, X.; Peng, Y.; Qu, L.; Yu, B.*, Metal-free sulfonyl radical-initiated cascade cyclization to access sulfonated indolo[1,2-a]quinolines,Chem. Commun.2019,55, 12615-12618.

4. Wei, Z.; Wu, X.; Luo, P.; Wang, J.;Li, K.*; Zang, S.*, Matrix coordination induced emission in a three-dimensional silver cluster-assembled material.Chem. Eur. J.2019,25, 2750-2756.

5. Liu, J.; Xing, C.; Wei, D.; Deng, Q.; Yang, C.; Peng, Q.; Hou, H.*; Li, Y.;Li, K.*, Utilizingaggregation-induced emission phenomenon to visualize spontaneous molecular directed motion in solid state,Mater. Chem. Front.2019,3, 2746-2750.

6. He, Y.;Li, Y.; Su, H.; Si, Y.; Liu, Y.; Peng, Q.; He, J.; Hou, H.*;Li, K.*, An o-phthalimide-based multistimuli-responsive aggregation-induced emission (AIE) system.Mater. Chem. Front.2019,3, 50-56.

7. Li, Y.; He, W.; Peng, Q.; Hou, L.; He, J.;Li, K.*, Aggregation-induced emission luminogen based molecularly imprinted ratiometric fluorescence sensor for the detection of Rhodamine 6G in food samples.Food. Chem.2019,287, 55-60.

8. Yang, C.; Li, Y.; Wang, J.; He, J.; Hou, H;Li, K.*, Fast and highly selective detection of acetaldehyde in liquor and spirits by forming aggregation-induced emissionluminogen.Sens. Actuators B: Chem.2019,285, 617-624.

9. Li, Y.; Peng, Q.*; Li, S.; Cai, Y.; Zhang, B.; Sun, K.; Ma, J.; Yang, C.; Hou, H.; Su, H.*;Li, K.*, A multifunctional quinoxalin-based AIEgen used for fluorescent thermo-sensing and image-guided photodynamic therapy,Sens. Actuators B: Chem.2019,301, 127139.

10. Xie, Q.; Shao. Z.; Zhao, Y.; Yang, L.; Wu, Q.; Xu, W.;Li, K.*; Song, Y.; Hou, H.*, Novel photo-controllable third-order nonlinear optical (NLO) switches based on azobenzene derivatives.Dyes Pigments2019,170, 107599.

11. Li, Y.; Xu, K.; Si, Y.; Yang, C.; Peng, Q.; He, J.; Hu, Q.*;Li, K.*, An aggregation-induced emission (AIE) fluorescent chemosensor for the detection of Al(III) in aqueous solution.Dyes Pigments2019,171, 107682.

12. Li, Y.; Peng, Q.; Li, S.; Yang, C.; He, J.; Hu, Q.*;Li, K.*, Facile synthesis of a photoresponsive AIEgen used for monitoring UV light and photo-patterning.Dyes Pigments2019,171, 107750.

13. Li, Y.; Li, Y.; Feng, Z.; Peng, Q.; Yang, C.; He, J.; Hu, Q.*;Li, K.*, An AIEgen-based luminescent photo-responsive system used as concealed anti-counterfeit material,J. Lumin.2019,216, 116750.

14. Li, Y.; Hou, L.; Shan F.; Zhang, Z.; Li, Y.; Liu, Y.; Peng, Q.; He, J.;Li, K.*, A Novel aggregation-induced emission luminogen based molecularly imprinted fluorescence sensor for ratiometric determination of Rhodamine B in food samples,ChemistrySelect2019,4, 11256-11261.

2018

1. Xu, K.; Li, Y.*; Su, H.; Wang, B.; Sun, K.; Liu, Y.; Peng, Q.; Hou, H.*;Li, K.*,Photo-induced free radical production in a tetraphenylethylene ligand-based metal-organic framework.Chem. Commun.2018,54, 12942-12945.

2. Li, K.*; Feng, Q.; Niu, G.; Zhang, W.; Li, Y.; Kang, M.; Xu, K.; He, J.; Hou, H.*; Tang, B. Z.*,Benzothiazole-based AIEgen with tunable excited-state intramolecular proton transfer and restricted intramolecular rotation processes for highly sensitive physiological pH sensing.ACS Sens.2018,3, 920-928.

3. Sun, K.; Chen, X. L.*; Li, S. J.; Wei, D. H.; Liu, X. C.; Zhang, Y. L.; Liu, Y.; Fan, L. L.; Qu, L. B.; Yu, B.*;Li, K.*; Sun, Y., Q.*; Zhao, Y. F., Copper-catalyzed radical cascade cyclization to access 3-sulfonated indenones with the AIE Phenomenon.J. Org. Chem.2018,83,14419-14430.

4. Li, K.*; Wang, J.; Li, Y.; Si, Y.; He, J.; Meng, X.; Hou, H.*; Tang, B. Z.*, Combining two different strategies to overcome the aggregation caused quenching effect in the design of ratiometric fluorescence chemodosimeters for pH sensing.Sens. Actuators B: Chem.2018,274, 654-661.

5. Liu, Y.; Li, Y.*; Feng, Q.;Li, K.*; Hou, H.; Zhang, B., “Turn‐on” fluorescent chemosensors based on naphthaldehyde‐2‐pyridinehydrazone compoundsfor the detection of zinc ion in water at neutral pH.Luminescence2018,33, 29-33.

6. Xu, K.; Li, Y.; Si, Y.; He, Y.; Ma, J.; He, J.; Hou, H.*;Li, K.*, A “turn-on” fluorescent chemosensor for the detection of Hg(II) in buffer-free aqueous solution with excellent selectivity.J. Lumin.2018,204, 182-188.

2017

1. Li, K.*; Liu, Y.; Li, Y.; Feng, Q.; Hou, H.*; Tang, B. Z.*,2, 5-bis(4-alkoxycarbonylphenyl)-1,4-diaryl-1,4-dihydropyrrolo[3,2-b]pyrrole (AAPP) AIEgens: tunable RIR and TICT characteristics and their multifunctional applications.Chem. Sci.2017,8, 7258-7267.

2. Wang, J.; Li, Y.;Li, K.*; Meng, X.; Hou, H.*, Highly selective turn-on fluorescent chemodosimeter for Al(III) detection via Al(III)‐promoted hydrolysis of carbon‐nitrogen double bond in 8-hydroxyquinoline aldehyde Schiff base.Chem. Eur. J.2017,23, 5081-5089.

3. Li, Y.;Li, K.*; Wang, L.; He, Y.; He, J.; Hou, H.*; Tang, B. Z.*, Fluoran salicylaldehyde hydrazone Zn(II) complexes: reversible photochromic systems both in solution and in a solid matrix.J. Mater. Chem. C2017,5(30), 7553-7560.

4. Wang, L.; Li, Y.; You, X.; Xu, K.; Feng, Q.; Wang, J.; Liu, Y.;Li, K.*; Hou, H.*, An erasable photo-patterning material based on a specially designed 4-(1, 2, 2-triphenylvinyl) aniline salicylaldehyde hydrazone aggregation-induced emission (AIE) molecule.J. Mater. Chem. C2017,5(1), 65-72.

5. Li, Y.;Li, K.*; Tang, B. Z.*,A photoactivatable photochromic system served as self-hidden information storage material.Mater. Chem. Front.2017,1, 2356-2359.

6. Li, Y.;Li, K.*; He, J., Domain structures and phase transitions in diisopropylammonium bromide molecular ferroelectric crystal.Chem. Phys. Lett.2017,689, 174-178.

7. Feng, Q.; Li, Y.;Li, K.*; Lu, J.; Wang, J.; Fan, P.; Li, D.; Wu, D.; Hou, H.*,Fluorescent chemosensor for zinc ion detection with significant emission color change in aqueous solution based on AIEgen.ChemistrySelect2017,2, 3158-3162.

8. Hou, B.;Li, K.*,Cu(I)/Cu(II) complexes based on a tetrazole derivative and the study about the degradation of organic dye under visible light irradiation.Chinese J. Inorg. Chem.2017,33(6), 1007-1014.

9. 李恺*,李媛媛,臧双全,唐本忠*.具有聚集诱导发光(AIE)性能的水杨醛希夫碱的合成与性能研究综合实验.化学教育,2017,38, 38-41.

10. 李媛媛,侯不唯,李恺*.基于水杨醛席夫碱结构的锌离子选择性荧光探针.化学研究,2017,28(2), 177-184.

2016

11. Feng, Q.; Li, Y.; Wang, L.; Li, C.; Wang, J.; Liu, Y.;Li, K.*; Hou, H.*,Multiple-color aggregation-induced emission (AIE) molecules as chemodosimeters for pH sensing.Chem. Commun.2016,52(15), 3123-3126.

12. Feng, Q.; Li, Y.; Shi, G.; Wang, L.; Zhang, W.;Li, K.*; Hou, H.*; Song, Y.*,Aphoto-controllable third-order nonlinear optical (NLO) switch based on a rhodamine B salicylaldehyde hydrazone metal complex.J. Mater. Chem. C2016,4(36), 8552-8558.

13. Li, Y.;Li, K.*; He, J., A “turn-on” fluorescent chemosensor for the detection of Zn (II) in aqueous solution at neutral pH and its application in live cells imaging.Talanta2016,153, 381-385.

14. Li, Y.*;Li, K.*; He, J., A ‘turn‐on’ fluorescent chemosensor for quantification of serum albumin in aqueous solution at neutral pH.Luminescence2016,31, 905-910.

2015

15. Shao, Z.; Huang, C.; Han, X.; Wang, H.; Li, A.; Han, Y.;Li, K.*; Hou, H.*; Fan, Y., The effect of metal ions on photocatalytic performance based on an isostructural framework.Dalton Trans.2015,44(28), 12832-12838.

16. Li, K.*; Li, Y.; Tao, J.; Liu, L.; Wang, L.; Hou, H.; Tong, A.*,Crystal violet lactone salicylaldehyde hydrazone Zn(II) complex: a reversible photochromic material both in solution and in solid matrix.Sci. Rep.2015,5, 14467-14467.

 

2014年以前

17. Li, K.; Xiang, Y.; Wang, X.; Li, J.; Hu, R.; Tong, A.*; Tang, B. Z.*, Reversible photochromic system based on rhodamine B salicylaldehyde hydrazone metal complex.J. Am. Chem. Soc.2014,136(4), 1643-1649.

18. Li, K.; Xiang, Y.; Tong, A.*; Tang, B. Z.*, Readily accessible Rhodamine B-based photoresponsive material.Sci. China Chem.2014,57(2), 248-251.

19. Li, K.; Wang, X.; Tong, A.*, A “turn-on” fluorescent chemosensor for zinc ion with facile synthesis and application in live cell imaging.Anal. Chim. Acta2013,776, 69-73.

20. Li, K.; Tong, A.*, A new fluorescent chemosensor for Zn2+with facile synthesis:“turn-on” response in water at neutral pH and its application for live cell imaging.Sens. Actuators B: Chem.2013,184, 248-253.

21. Li, K.; Li, N.; Chen, X.; Tong, A.*, A ratiometric fluorescent chemodosimeter for Cu (II) in water with high selectivity and sensitivity.Anal. Chim. Acta2012,712, 115-119.

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