石林林

作者: 时间:2021-01-15 点击数:

姓名:石林林

性别:男

出生年月:1992.09

职称:直聘副教授

名族汉族

籍贯:安徽安庆

电子邮箱:linlinshi@zzu.edu.cn

学位:理学博士北京大学

研究方向:有机合成,功能分子有机全合成与性质探究天然产物全合成

主要学习、科研和工作经历

教育经历:

2014--2019北京大学(直博),博士(导师:杨震,龚建贤教授)

2019-至今 郑州大学化学学院,直聘副教授,硕士生导师

代表性教学成果与荣誉

北京大学三好学生;北京大学优秀学生干部;

北京大学五四奖学金;药明康德学术二等奖学金;

北京大学-普林斯顿双边论坛-优秀奖学金

主持项目:

中国博士后面上基金

国家自然科学基金青年基金

郑州大学拔尖启动基金

代表性科研成果

1. Yuanyuan Chang,Linlin Shi, Jun Huang, Lili Shi, Zichun Zhang, Hong-Dong Hao, Jianxian Gong and Zhen Yang. Stereoselective Total Synthesis of (±)-5-epi-Cyanthiwigin I via an Intramolecular Pauson−Khand Reaction as the Key Step.Org. Lett.2018,20, 2876-2879.

2.Linlin Shi, Yingdong He, Yuanyuan Chang, Nan Zheng, Zhen Yang, and Jianxian Gong. Stereoselective Pd-Catalyzed Decarboxylative Allylation: Assembly of Highly Functionalized Allylic Amines Bearing a Quaternary Center.Org. Lett.2019,21, 3077-3080.

3.Linlin Shi, Yingdong He, Jianxian Gong and Zhen Yang. Pd-Catalyzed Decarboxylative Allylation for Stereoselective Syntheses of Allylic Alcohols bearing a Quaternary Carbon Center.Asian J. Org. Chem.2019,8, 823-827.

4.Linlin Shi, Yingdong He, Jianxian Gong and Zhen Yang. Concise gram-scale synthesis of Euphorikanin A skeleton through a domino ring-closing metathesis strategy.Chem. Commun.2020,56, 531-534.

5.Linlin Shi, Yingdong He, Jianxian Gong and Zhen Yang. Palladium-Catalyzed Domino Decarboxylation/Carbonylation/ Cyclization Process for the Synthesis of Highly Substituted δ-Lactones and lactams.Organometallics.2020. doi.org/10.1021/acs.organomet.0c00646.

6. Changlei Zhi, Qiuling Wang, Shuang Liu, Yuting Xue,Linlin Shi,*Xinju Zhu, Xin-Qi Hao, and Mao-Ping Song.* Cu-Catalyzed Direct C7-Sulfonylation of Indolines with Arylsulfonyl Chlorides.J. Org. Chem.2020,85, 1022-1032.

7. Zilin Liu, Xiaojie Zhang, Heng Zhang, Hui Jiang, Xuemei Zhao,*Linlin Shi,*Xinju, Zhu, Xinqi Hao, Maoping Song. Phathalocyanine Metal Complexes (M=Fe, Co, and Cu) Catalyzed Aerobic Oxidation of 2-Amino- benzyl Alcohols to Access Quinazolines and Quinolines.Chin. J. Org. Chem.2020,40, 2755-2763. (Cover Article)

8. Qiuling Wang,Linlin Shi, Shuang Liu, Changlei Zhi, Lian-Rong Fu, Xinju Zhu,* Xin-Qi Hao, and Mao-Ping Song.* Solvent-free and room temperature microwave-assisted direct C7 allylation of indolines via sequential C-H and C-C activation.RSC Adv.2020, 10,10883-10887.

9.Linlin Shi, Jing Li, Shu-Ping Zhang, Xu-Yan Wang, Xinju Zhu,* Xin-Qi Hao, Mao-Ping Song.* Rh(III)-Catalyzed C−H Cyanation of 2HIndazole with NCyanoNphenylptoluene sulfonamide.J. Org. Chem.2020,85, 10835-10845.

10.Linlin Shi, Jing Yan, Yan‐Bing Wang, Senyao Hou, Xinju Zhu, Xin‐Qi Hao, Mao‐Ping Song. NCC Pincer Ni (II) Complexes Catalyzed Hydrophosphination of Nitroalkenes with Diphenylphosphine.Appl Organomet Chem.2020, 5954.

11. Ya-Gai Wang, Jing Li, Xiao-Die Wang,Linlin Shi.* Xinju Zhu, Xin-Qi Hao, Mao-Ping Song. Rh(III)-catalyzed C–H acylmethylation of 2H-indazoles with sulfoxonium ylides. Journal of Saudi Chemical Society,2020,24, 850-856.

12. Zilin Liu, Xiaomin Wan, Huating Yan, Xuyan Wang,Linlin Shi,* Xinqi Hao and Maoping Song. NNN Pincer Ru(II)-Catalyzed Dehydrogenative Coupling of 2-Aminoarylmethanols with Nitriles for the Construction of Quinazolines. CCS· The 16th National Synthetic Organic Chemistry Symposium.

13.Changlei Zhi, Enling Huang, Xiaodie Wang, Binghui Liu,Linlin Shi,* Xinqi Hao and Maoping Song. Oxidative Sulfonamidomethylation of Imidazopyridines Utilizing Methanol as Main C1 Source. CCS·The 16th National Synthetic Organic Chemistry Symposium.

14.Jingna Wei, Zhaodong Jia, Ning Zhang,Linlin Shi,* Yan Xu, Xinqi Hao and Maoping Song. A new colorimetric and fluorescent chemosensor based on thiazolyl-hydrazone for sensitive detection of copper ions. CCS·The 16th National Synthetic Organic Chemistry Symposium.

15.Guoxing Liu,Juhua Leng,Qingyang Zhou,Zhe Deng,Linlin Shi,Cailing Fan,Xiufang Xu,Mao-PingSong,Dyes and Pigments.https://doi.org/10.1016/j.dyepig.2022.110361.

16.Linlin Shi,Dongdong An, Guang-Jian Mei*. Difluoromethylation of heterocycles via a radical process.Org. Chem. Front.2022. 10.1039/d2qo00762b.

17.Guoxing Liu, Juhua Leng, Qingyang Zhou, Zhe Deng,Linlin Shi*,Cailing Fan*. Fluorescence photoswitch of stiff-stilbene derivatives for anti-counterfeiting.Dyes and Pigments,2022,203, 110361.

18.Yu-Shen Zhu,Linlin Shi(First Author),Lianrong Fu, Xiran Chen, Xinju Zhu, Xin-Qi Hao, Mao-Ping Song*. Iodine-catalyzed amination of benzothiazoles with KSeCN in water to access primary 2-aminobenzothiazoles.Chin. Chem. Lett.2022, 33, 1497-1500.

19. Yuting Xue,Linlin Shi,(First Author)Xu Wang, Xiaoni Yu, Xinju Zhu,* Xin-Qi Hao,* Mao-Ping Song. Regioselective N-F and α C(sp3)-H Arylation of Aliphatic NFluorosulfonamides with Imidazopyridines.Org. Lett.2021,23, 6807.

20.Wenxiu Liu,Guoxing Liu,Xinju Zhu,Xin Han,Anting Lu,Shuai Lu,Linlin Shi,Xin-Qi Hao,Mao-PingSong,2022,doi.org/10.1039/D2NJ00382A.

21.Ling-ling Miao,Xinju Zhu,Guoxing Liu,Xin Han,Wenping Xie,Shuai Lu,Long Zhang,Kai Wang,Linlin Shi,Xin-Qi Hao and Mao-Ping Song,Chin. Chem. Lett.2022, Accepted

22. Jing-Jing Qu,Linlin Shi,Yan-Bing Wang, Jing Yan, Tian Shao, Xin-Qi Hao, Jia-Xiang Wang, Hong-Yu Zhang, Jun-Fang Gong and Bing Song, Molecules2022, 27(10), 3106;https://doi.org/10.3390/molecules27103106.

23.Tiantian Li, Xinju Zhu, Hui Jiang,Linlin Shi,*Xin-Qi Hao, Mao-Ping Song.* Pd-catalyzed decarboxylative [3+2] cycloaddition: Assembly of highly functionalized spirooxindoles bearing two quaternary centers. Appl Organomet Chem., 2021, https://doi.org/10.1002/aoc.6516

24.Linlin Shi,*Tiantian Li, Guang-Jiang Mei.* Recent advances in transition-metal-free C–H functionalization of imidazo[1,2-a]pyridines. Green Synth. Catal., 2022, https://doi.org/10.1016/j.gresc.2022.03.007 ( #contributed equally)

25. Tiantian Li,Linlin Shi,*Xin-Qi Hao, * Mao-Ping Song.* Visible-Light- Promoted Direct C(sp2)-H Radical Difluoromethylation of Duinoxalinones and Difluorosulfones. (manuscript in preparation)

26. Juanzi Lianglu, Weinan Hu, Xinju Zhu, Hong-Yu Zhang,*Linlin Shi,*Xin-Qi Hao, Mao-Ping Song. Synthesis of a Tetrahedral Metal–Organic Supramolecular Cage with Dendritic Carbazole Arms. Int. J. Mol. Sci., 2022,https://doi.org/10.3390/ijms232415580.

27. Xin Jin, Hui Jiang, Yi Chen, Xin Han, Ken Sun,Linlin Shi,*Xin-Qi Hao,* and Mao-Ping Song. A Cavity-Tailored Metal-Organic Tetrahedral Nanocage and Gas Adsorption Property. Nanomaterials., 2022,https://doi.org/10.3390/nano12244402.

28. Xin Han, Weinan Hu, Lingling Miao, Xin-Qi Hao,Linlin Shi*, Mao-Ping Song*. Structurally coordinated aggregation induced emission ionic supramolecular cages. Dyes and Pigments 2023,https://doi.org/10.1016/j.dyepig.2023.111078.

29.Xin Han, Chenxing Guo, Chen Xu,Linlin Shi, Binghui Liu, Zhe Zhang, Qixia Bai, Bo Song, Fangfang Pan, Shuai Lu, Xinju Zhu, Heng Wang*, Xin-Qi Hao*, Mao-Ping Song*, Xiaopeng Li*. Water-Soluble Metallo-Supramolecular Nanoreactors for Mediating Visible-Light-Promoted Cross-Dehydrogenative Coupling Reactions. ACS Nano 2023,https://doi.org/10.1021/acsnano.2c10856.

30.Linlin Shi, Siyu Lu.Efficient bottom-up synthesis of graphene quantum dots at an atomically precise level. Matter. 2023, doi.org/10.1016/j.matt.2023.01.003.

31.Linlin Shi, Boyang Wang, Siyu Lu. Precise carbon dots synthesis: building bridges between organic chemistry and inorganic chemistry. Science Bulletin.doi.org/10.1016/j.scib.2022.11.013.

32.Linlin Shi,Dongdong An, Guang-Jian Mei*. Difluoromethylation of heterocycles via a radical process.Org. Chem. Front.2022. 10.1039/d2qo00762b.

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