宋西西，副教授，中国民主同盟盟员
电子邮箱：xixisong@zzu.edu.cn
学习经历
1. 1999-2003，郑州大学，化学系，理学学士，导师：徐顺教授。
2. 2003-2006，武汉大学，化学与分子科学学院，研究生，张华山教授。
3. 2006-2008，美国北达科他州立大学，理学硕士，Gregory Cook教授。
4. 2008-2012，美国新墨西哥大学，理学博士，导师：王卫教授。
工作经历
1. 2012-2015，郑州大学，化学学院，讲师
2. 2013-2017，郑州大学，化学学院，博士后，导师：常俊标教授。
3. 2015-至今，郑州大学，化学学院，副教授
研究方向
新型有机合成方法学的研发，功能性化合物的合成与应用
主持项目
1.国家自然科学基金青年基金项目：双核金属配合物对串联反应的不对称催化研究，21302173，2014-2016，主持，已完成。
2.中国博士后科学基金第五十四批面上二等资助项目：双核金属配合物在不对称串联反应中的应用，2013M541984，2013-2015，主持，已完成。
3.中国博士后科学基金第七批特别资助项目：双核锌配合物催化的手性偶氮化合物的不对称合成，2014T70681，2014-2017，主持，已完成。
4.横向项目：磷酰功能化季铵离子液体的定制合成，2018-2019，主持，已完成。
5.河南省高等学校重点科研项目：对亚甲基苯醌类化合物与苄卤的串联反应方法研究，19A150049，2019-2020，主持，已完成。
发表论文
[1] Minli Zhang, Tong Li, Chaoxing Cui, Xixi Song,* Junbiao Chang.* Stereoselective Sequential Spirocyclopropanation/Cloke–Wilson Rearrangement Reactions for Synthesis of trans-β,γ-Disubstituted γ-Butyrolactones Using Alkylidene Meldrum’s Acid and Benzyl Halides.The Journal of Organic Chemistry2020,85, 2266-2276.
[2] Xixi Song, Yueteng Zhang, Peng Ji, Fanxun Zeng, Fangchao Bi, Wei Wang.* One-pot synthesis of salicylaldehyde containing biaryl frameworks via an aminocatalytic Diels-Alder-retro-Diels-Alder cascade reaction of ynals with 2-pyrones.Green Synthesis and Catalysis2020,1, 66-69.
[3] Tong Li, Dandan Yan, Chaoxing Cui, Xixi Song,* Junbiao Chang.* A thermal decarboxylative Cloke–Wilson rearrangement of dispirocyclopropanes derived from para-quinone methides and bromo-Meldrum's acids: an approach to synthesize spirobutyrolactone para-dienones.Organic Chemistry Frontiers2020,7, 2682-2688.
[4] Yuanyuan Zhu, Shuang Zhao, Minli Zhang, Xixi Song,* Junbiao Chang.* Diastereoselective Synthesis of Spirobarbiturate-Cyclopropanes through Organobase-Mediated Spirocyclopropanation of Barbiturate-Based Olefins with Benzyl Chlorides.Synthesis2019,51, 899-906.
[5] Yuanyuan Zhu, Minli Zhang, Tong Li, Xixi Song.* AlCl3-Promoted Stereospecific Cloke-Wilson Rearrangement of Spirocyclopropyl Barbiturates for the Synthesis of Substituted Dihydrofuro[2,3-d]pyrimidines.ChemistrySelect2019,4, 10838-10842.
[6] Shangkun Zhao, Yuanyuan Zhu, Minli Zhang, Xixi Song,* Junbiao Chang.* Base-Mediated Tandem 1,6-Addition/Cyclization/Isomerization Reactions between para-Quinone Methides and Benzyl Chlorides: Approaches to Diverse Frameworks at Each Cascade Stage.Synthesis2019,51, 2136-2148.
[7] Xuebin Yan,* Pei Shao, Xixi Song, Chaofei Zhang, Chang Lu, Songtao Liu, Yanli Li. Chemoselective syntheses of spirodihydrofuryl and spirocyclopropyl barbiturates via cascade reactions of barbiturate-based olefins and acetylacetone.Organic & Biomolecular Chemistry2019,17, 2684-2690.
[8] Yinan Zhang, Xixi Song, Xiaobei Chen, Aiguo Song, Shilei Zhang, Wei Wang.* Enantioselective Construction of Functionalized Cyclopentanes by a Relay Ring-Closing Metathesis and Chiral Amine (Thio)urea-Promoted Michael Addition.Synthesis2014,46, 2601-2607.
[9] Xixi Song, Wei Wang, inComprehensive Organic Synthesis II (Second Edition)(Ed.: P. Knochel), Elsevier, Amsterdam,2014, pp. 86-118.
[10] Xixi Song, Jing Liu, Meng-Meng Liu, Xi Wang, Zhao-Fei Zhang, Min-Can Wang,* Junbiao Chang.* Dinuclear zinc catalyzed asymmetric tandem Michael addition/acetalization reactions of cyclic diketones and β,γ-unsaturated α-ketoesters.Tetrahedron2014,70, 5468-5474.
[11] Xixi Song, Ai-Xiang Liu, Shan-Shan Liu, Wen-Chao Gao, Min-Can Wang,* Junbiao Chang.* Enantiopure azetidine-2-carboxamides as organocatalysts for direct asymmetric aldol reactions in aqueous and organic media.Tetrahedron2014,70, 1464-1470.
[12] Xixi Song, Yuan-Zhao Hua, Jing-Guo Shi, Ping-Ping Sun, Min-Can Wang,* Junbiao Chang.* Diastereomeric Aziridine Carbinol Catalyzed Enantioselective Arylation Reaction: Toward the Asymmetric Synthesis of Both Enantiomers of Chiral 3-Aryl Phthalide.The Journal of Organic Chemistry2014,79, 6087-6093.
[13] Xinshuai Zhang, Xixi Song, Hao Li, Shilei Zhang, Xiaobei Chen, Xinhong Yu,* Wei Wang.* An Organocatalytic Cascade Approach toward Polysubstituted Quinolines and Chiral 1,4-Dihydroquinolines–Unanticipated Effect of N-Protecting Groups.Angewandte Chemie International Edition2012,51, 7282-7286.
[14] Xixi Song, Xinshuai Zhang, Shilei Zhang, Hao Li,* Wei Wang.* Direct Transformation of Simple Enals to 3,4-Disubstituted Benzaldehydes under Mild Reaction Conditions via an Organocatalytic Regio- and Chemoselective Dimerization Cascade.Chemistry – A European Journal2012,18, 9770-9774.
[15] Xixi Song, Aiguo Song, Fang Zhang, He-Xing Li,* Wei Wang.* Direct stereoselective α-arylation of unmodified enals using an organocatalytic cross-coupling-like reaction.Nature Communications2011,2, 524.
