田荣强

作者: 时间:2021-01-21 点击数:

http://grjl.hnu.edu.cn/content/clxy/images/jy.png基本信息

田荣强,博士,副教授,硕士生导师。办公电话:0371-67783393;电子邮箱:tianrq@zzu.edu.cn;通讯地址:河南省郑州市科学大道100号。

http://grjl.hnu.edu.cn/content/clxy/images/jy.png教育背景

2001-2005聊城大学 化学化工学院 学士

2005-2010郑州大学 化学学院 博士(硕博连读)

http://grjl.hnu.edu.cn/content/clxy/images/jy.png工作履历

2010-2012新加坡南洋理工大学 数理学院 博士后

2012-至今 郑州大学化学学院

http://grjl.hnu.edu.cn/content/clxy/images/jy.png研究领域

有机磷化学,金属有机化学

主要从事含磷杂环化合物的合成及反应研究,发现新的磷化学反应,揭示反应规律。

http://grjl.hnu.edu.cn/content/clxy/images/jy.png研究成果(Selected publications

2014-2016“具有磷杂二茂铁骨架的π酸配体合成及其催化性能研究”,国家自然科学基金资助项目(编号201302174),已结项.

2017磷杂富烯类化合物的合成、反应性能及机理研究,中国博士后科学基金面上资助(1621316006)。

2017-2019过渡金属催化的C-P键断裂及相关化学反应研究,郑州大学优秀青年发展基金,(1621316006)。

2020-2021新型π酸配体的合成及其在异丁烯制备异戊醛工艺中的应用,河南省高等学校重点科研项目(20A150040)

2020-2021环张力促进的C-P键的转化、机理及应用,郑州大学青年教师(自然科学)基础研究培育基金(JC202053019)

代表性论文:

1. Yanjie Liu, Keke Zhang,Rongqiang Tian,*Zheng Duan,* and François Mathey,1,1-Addition of α‑C2‑Bridged Biphospholes with Alkynes,Org. Lett.2020,22, 6972−6976,

2. Min Wang, Tingting Yang,Rongqiang Tian,* Donghui Wei, * Zheng Duan * and Francois Mathey, The chemistry of phosphirane-substituted phosphinidene complexes,Chem. Commun.2020, 56, 9707-9710

3. Juan Li, Mingyue Cui,Rongqiang Tian*, Zheng Duan*, François Mathey, Cycloadditions of 1-iminylphosphirane complexes with allenes,Chinese Chem. Lett.2020,https://doi.org/10.1016/j.cclet.2020.05.026

4. Yang Xu, Chenyang Jiao, Juan Li,Rongqiang Tian,* Zheng Duan,* and François Mathey,An Approach to Peri-Fused Heterocycles: A Metal-Mediated Cascade Carbonylative Cyclization/Dearomatic Diels−Alder Reaction.Org. Lett.2019,21, 9512−9515

5. Min Wang, Yang Xu, Donghui Wei,Rongqiang Tian,* Zheng Duan,* and Francois Mathey, Transition-Metal-Like Reversible Cycloadditions of [tBuSP-W(CO)5] with Alkenes and Alkynes.Chem. Eur. J.2019,25, 15036– 15039

6. Yang Xu, Min Wang, Donghui Wei,Rongqiang Tian,*Zheng Duan* and François Mathey* An approach to 7-aza-1-phosphanorbornane complexes: strain promoted rearrangement of 1-iminylphosphirane complexes and cycloaddition with olefins.Dalton Trans.2019,48, 5523-5526

7. Jinkui Chai,Rongqiang Tian,*Di Wu, Donghui Wei, Qun Xu, Zheng Duan* and François Mathey,* The coordination chemistry of phosphinidenes sulfides. Synthesis and catalytic properties of Pd4 and Pt4 clusters.Dalton Trans.2018,47, 13342–13344

8.Rongqiang Tian,* Chunli Zhang, Yang Xu, Chenguang Liu, Zheng Duan,* and François Mathey, The Chemistry of 1-Acylphosphirane Complexes: A Phosphorus Analogue of the Cloke–Wilson Rearrangement,Chem. Eur. J.2017,23, 13006 – 13009

9. Zhengsong Hu,Rongqiang Tian,* Kang Zhao, Yanjie Liu, Zheng Duan,* and François Mathey ̧ * Generation and Trapping of a 1‑Phosphafulvene: An Illustration of the P=C/C=C Analogy,Org. Lett.2017,19, 5004-5006

10. Yanwei Hao, Di Wu,Rongqiang Tian,* Zheng Duan* and François Mathey*, Insertion of phosphinidene complexes into the P–H bond of secondary phosphine oxides: a new version of the phospha-Wittig synthesis of P=C double bonds,Dalton Trans.2016,45, 891–893.

11. Yanwei Hao, Chunli Zhang, Yanbo Mei,Rongqiang Tian,* Zheng Duan* and François Mathey*, The chemistry of parent phosphiranide in the coordination sphere of tungsten,Dalton Trans.2016,45, 8284–8290

12. Jonathan Wong, Yongxin Li, Yanwei Hao,Rongqiang Tian,*and François Mathey.* Isomerization of Secondary Phosphirane into Terminal Phosphinidene Complexes: An Analogy between Monovalent Phosphorus and Transition Metals.Angew. Chem. Int. Ed.2015,54, 12891 –12893

13. Zhengsong Hu, Zongyang Li, Kang Zhao,Rongqiang Tian,* Zheng Duan,*and François Mathey.* Reaction of Phospholes with Aldimines: A One-Step Synthesis of Chelating, Alpha-C2-Bridged Biphospholes.Org. Lett.2015,17, 3518−3520

14.Rongqiang Tian,* Yanbo Mei, Zheng Duan,*, and François Mathey*, Simple Access to Tungsten-Stabilized Disecondary Diphosphines,Organometallics2013,32, 5615−5618

15.Rongqiang Tianand François Mathey, The Insertion of Terminal Phosphinidene Complexes into the B-H Bond of Amine and Phosphine Boranes.Chem. Eur. J.2012,18, 11210-11213.

16.Rongqiang Tian, Hui Liu, Zheng Duan, and François Mathey, The Abnormal Hydrolysis of 7-Phosphanorbornenium Salts: A Case of Phosphonium-Phosphenium Equivalence.J. Am. Chem. Soc.2009,131, 16008-16009.

http://grjl.hnu.edu.cn/content/clxy/images/jy.png奖励与荣誉(Selected honors/awards

河南省优秀科技论文壹等奖 证书编号:豫教[2014]05640

河南省优秀科技论文壹等奖 证书编号:豫教[2014]05641

2016-2017学年郑州大学“三育人”先进个人

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