武杰

作者: 时间:2021-01-21 点击数:

武杰,教授、博士生导师,河南省青年骨干教师,河南省教育厅学术技术带头人

邮箱:wujie@zzu.edu.cn

主要学习、科研和工作经历

2016年5月-至今 郑州大学化学学院 教授

2017年-2018年 Northwestern University (hupp and farha group) 访问学者

2010年5月-2016年4月 郑州大学化学学院 副教授

2007年9月-2010年4月 郑州大学化学学院 讲师

2002年9月-2007年6月 郑州大学化学系 硕博连读

主要研究方向:

1. 光催化MOFs材料的制备及催化性能研究

金属有机骨架材料作为一种新型多微孔晶态材料,凭借其独特的多孔性、可修饰性以及超高的比表面积,在催化领域获得了广泛的应用,有效结合了均相催化剂和非均相催化剂两者的优势,补充了传统微孔材料和介孔材料之间孔的尺寸的空白。

课题组设计合成新型的MOFs可见光催化剂;通过SIM法、半导体复合等方法进一步调节催化剂带隙结构,提高可见光催化效率;研究MOFs可见光催化剂在光催化水裂解,CO2还原,氮气还原等热门研究领域的应用。

2. MOFs材料催化有机合成反应研究

通过原位合成、后修饰等手段向MOFs材料中引入催化活性中心,结合MOFs材料多孔性特点,形成高效的非均相催化剂,应用于CO2环加成反应、化学战剂的降解等。

科研项目

1.国家自然科学基金面上项目,基于非贵金属配合物可逆结构转化诱导的氨气和小分子胺N-H键裂解及其在催化胺化反应中的应用(21771163),主持。

2.一类新药FNC技术02,横向,100万,主持

3.国家自然科学基金青年基金项目,基于D-A-D-A型不对称共轭四联氮杂环配体构筑的配体介导型金属有机骨架材料的研究(21201152),国家自然科学基金青年基金,主持

4.河南省自然科学基金面上项目,基于可控可逆氧化还原转化的新型晶态多孔金属—有机框架催化材料的研究(162300410243),主持

5.抗肿瘤胞苷类似物修饰的新型铂(II)药物分子的合成、表征及生物活性研究,国家博士后基金特别资助(201003401),主持

6.核苷类化合物金属药物分子修饰的研究,国家博士后基金一等资助(20090450095),主持

教学成果

主持承担河南省一流本科课程建设项目一项、河南省精品在线开放课程建设项目一项、河南省教育厅教师教育课程改革研究项目一项、郑州大学线下精品在线开放课程建设项目一项、郑州大学“MOOC”课程建设项目一项、国家级大学生创新创业项目一项。

近年来,在“Coord. Chem. Rev.”、、“Chem. Commun.”、“Chem. Eur. J”、“Inorg. Chem.”等上面发表SCI论文50余篇发。

代表性论文:

(1) Metal-Organic Framework (MOF)-Based Materials as Heterogeneous Catalysts for C-H Bond Activation.Chem-Eur J2019,25(12), 2935-2948。

(2) Cu(I)-Based Metal-Organic Frameworks as Efficient and Recyclable Heterogeneous Catalysts for Aqueous-Medium C-H Oxidation.Cryst Growth Des2019,19(2), 976-982.

(3) Co-Cluster-Based Metal–Organic Frameworks as Selective Catalysts for Benzene Tandem Acylation–Nazarov Cyclization to Benzocyclopentanone,Chem. Eur. J.,2018, 24, 1416-1424.

(4) Design, synthesis, and biological evaluation of new 1,2,3-triazolo-20-deoxy-20-fluoro- 40-azido nucleoside derivatives as potent anti-HBV agents,Eur. J. Med. Chem.2018,143, 137-149.

(5) Efficient Catalytic Performance for Acylation-Nazarov Cyclization Based on an Unusual Postsynthetic Oxidization Strategy in a Fe(II)-MOF,Inorg. Chem.2018,57, 10224-1031.

(6) Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C−H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect,Inorg. Chem.2017,56, 13329-13336.

(7) Solvent-Induced Assembly of Sliver Coordination Polymers (CPs) as Cooperative Catalysts for Synthesizing of Cyclopentenone[b]pyrroles Frameworks,Inorg. Chem.2017,56, 4874-4884.

(8) Crystalline central-metal transformation in metal–organic frameworks,Coor. Chem. Rev.2016, 307, 130-146.

(9) Surfactant-Assisted Nanocrystalline Zinc Coordination Polymers: Controlled Particle Sizes and Synergistic Effects in Catalysis.Chem. Eur. J.,2016, 22, 6389-6396.

(10)Reversible conversion of valence-tautomeric copper metal–organic frameworks dependent single-crystal-to-single-crystal oxidation/reduction: a redox-switchable catalyst for C–H bonds activation reaction,Chem. Comm.2015, 51, 10353-10356.

(11)Solvent Templates Induced Porous MetalOrganic Materials: Conformational Isomerism and Catalytic Activity,Inorg. Chem.2015,54, 1405-1413.

(12)Copper(II) Coordination Polymers: Tunable Structures and Different Activation Effect of Hydrogen Peroxide for the Degradation of Methyl Orange under Visible Light Irradiation,Dalton,2015,44, 1406-1411

(13)Template Induced Diverse Metal-organic Materials as Catalysts for Tandem Acylation-Nazarov Cyclization,Chem. Eur. J.2014,20, 16156-16163

(14)Structural Variability, Topological Analysis and Photocatalytic Properties of Neoteric Cd(II) Coordination Polymers Based on Semirigid Bis(Thiazolylbenzimidazole) and Different Types of Carboxylic Acid Linkers,Dalton,2014,43, 12790-12799.

(15)Metal–organic frameworks based on the [1,1':3',1'-terphenyl]-3,3'',5,5''-tetracarboxylic acid ligand: syntheses, structures and magnetic properties,Dalton,2014,43, 15475-15481.

(16)Design, synthesis, and biological evaluation of new 2'-deoxy-2'-fluoro-4'-triazole cytidine nucleosides as potent antiviral agents.Eur. J. Med. Chem.2013,63, 739-745.

(17)Solvent-Mediated Central Metals Transformation from a Tetranuclear NiII Cage to a Decanuclear CuII “Pocket”,Crystal Growth & Design,2010,10, 3835-3836.

(18)Construction of two discrete molecular high-nuclear copper(II) complexes as heterogeneous catalysts for oxidative coupling polymerization of 2, 6-dimethylphenol,Eur. J. Inorg. Chem.,2009, 2796-2803.

(19)3D Coordination Framework with Uncommon two-fold Interpenetrated {33·59·63}-lcy Net and Coordinated Anion Exchange,Chem. Eur. J.,2009,15, 4049-4056.

(20)Highly Selective Ferric Ion Sorption and Exchange by Crystalline Metal Phosphonates Constructed from Tetraphosphonic Acids,Inorg. Chem.,2007,46, 7960-7970.

(21)Studies on Cage-Type Tetranuclear Metal Clusters with Ferrocenylphosphonate Ligands,Chem. Eur. J.,2006,12, 5823-5831.

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