华远照，男，汉族，1979年07月生于河南省南阳市。 |
郑州大学化学学院，校聘副教授。 |
联系方式：15838251957 |
邮箱：hyzhao@zzu.edu.cn 通讯地址：河南省郑州市二七区大学路75号，郑州大学南校区22号楼417
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教育经历：
2011/09—2015/07：郑州大学化学与分子工程学院，有机化学，理学博士；
2002/09—2005/07：郑州大学化学系，有机化学，理学硕士；
1998/09—2002/07：郑州大学化学系，化学本科。
工作经历：
2016/08—至今，郑州大学，化学学院，校聘副教授
2008/07—2011/09，新乡医学院，基础医学院，讲师；
2005/07—2008/07，新乡医学院，基础医学院，助教；
研究领域：
新手性配体的设计与合成、不对称催化合成方法学研究
主持或参加科研项目：
1.国家自然科学基金面上项目，21871237，双核锌协同催化的不对称串联反应研究，2019/01—2022/12，65万元，在研，参与
2.中国博士后科学基金面上二等资助，2017M622361，半冠状多齿双噁唑啉手性配体的设计、合成及应用，2018/01-2019/12，5万元，在研，主持
3.国家自然科学基金面上项目，21272216，二氧化碳与环氧化物的催化不对称交替共聚反应研究，2012/01—2016/12，80万元，已结项，参与
研究成果：
1. Xiao-Chao Yang, Meng-Meng Liu, François Mathey, Hua Yang, Yuan-Zhao Hua(*), Min-Can Wang(*). Access to Chiral 2,5-Pyrrolidinyl Dispirooxindoles via Dinuclear Zinc-Catalyzed Asymmetric Cascade Reactions[J]. J. Org. Chem. 2019, 84, 7762−7775.
2. Meng-Meng Liu, Xiao-Chao Yang, Yuan-Zhao Hua,(*) Jun-Biao Chang(*), Min-Can Wang.(*) Dinuclear Zinc-Catalyzed Asymmetric Tandem Reaction of α-Hydroxy-1-indanone: Access to Spiro[1-indanone-5,2′-γ-butyrolactones][J]. Org. Lett. 2019, 21, 7089-7093.
3. Meng-Meng Liu, Xiao-Chao Yang, Yuan-Zhao Hua, Jun-Biao Chang(*), Min-Can Wang(*). Synthesis of Chiral Bispirotetrahydrofuran Oxindoles by Cooperative Bimetallic-Catalyzed Asymmetric Cascade Reaction[J]. Org. Lett. 2019, 21, 2111−2115.
4. Bing-Kai Tao, Hua Yang, Yuan-Zhao Hua(*), Min-Can Wang(*). Dinuclear zinc synergistic catalytic asymmetric phospha-Michael/Michael cascade reaction: synthesis of 1,2,3-trisubstituted indanes bearing phosphoryl groups[J]. Org. Biomol. Chem. 2019, 17, 4301−4310.
5. Yu-Hang Miao, Yuan-Zhao Hua and Min-Can Wang(*). Dinuclear zinc cooperative catalytic three-component reactions for highly enantioselective synthesis of 3,3’-dihydrofuran spirooxindoles[J]. Org. Biomol. Chem. 2019, 17, 7172–7181.
6. Yuan-Zhao Hua, Jun-Wei Chen, Hua Yang(*), and Min-Can Wang(*). Asymmetric Friedel–Crafts Alkylation of Indoles with Trifluoromethyl Pyruvate Catalyzed by a Dinuclear Zinc Catalyst[J]. J. Org. Chem. 2018, 83, 1160–1166.（中科院化学二区）
7. Yuan-Yuan Gao, Yuan-Zhao Hua(*), Min-Can Wang(*). Asymmetric 1,6-Conjugate Addition of para-Quinone Methides for the Synthesis of Chiral β,β-Diaryl-α-Hydroxy Ketones[J]. Adv. Synth. Catal. 2018, 360, 80–85.
8. Na Shao, Yong-Yang Luo, Hui-Jie Lu, Yuan-Zhao Hua(*), Min-Can Wang(*). Enantioselective phospha-Michael reaction of diethyl phosphonate with exocyclic α,β-unsaturated benzocyclic ketones catalyzed by a dinuclear zinc−AzePhenol catalyst[J]. Tetrahedron 2018, 74, 2130-2142.
9. Yuan-Zhao Hua, Xing-Wang Han, Li-Hua Huang(*), Min-Can Wang(*). Asymmetric Friedel-Crafts Alkylation of Pyrrole with Chalcones Catalyzed by a Dinuclear Zinc Catalyst[J]. Chin. J. Org. Chem. 2018, 38, 237–248.
10. Xin-Wei Wang, Yuan-Zhao Hua(*), Min-Can Wang(*). Synthesis of 3-Indolylglycine Derivatives via Dinuclear Zinc Catalytic Asymmetric Friedel-Crafts Alkylation Reaction[J]. J. Org. Chem. 2016, 81, 9227–9234.
11. Yuan-Zhao Hua, Xiao-Chao Yang, Meng-Meng Liu, Xixi Song, Min-Can Wang(*) and Jun-Biao Chang(*). Asymmetric Copolymerization of Cyclopentene Oxide and CO2 Using a Dinuclear Zinc-AzePhenol Catalyst: Enlightened by DFT Calculations[J]. Macromolecules 2015, 48, 1651–1657.
12. Yuan-Zhao Hua, Meng-Meng Liu, Pei-Jin Huang, Xi-Xi Song, Min-Can Wang(*), and Jun-Biao Chang(*).A New Strategy for Enantioselective Construction of Multisubstituted Five-Membered Oxygen Heterocycles via a Domino Michael/Hemiketalization Reaction [J]. Chem.–Eur. J. 2015, 21, 11994–11998.
13. Yuan-Zhao Hua, Liu-Jie Lu, Pei-Jin Huang, Dong-Hui Wei, Ming-Sheng Tang, Min-Can Wang(*), and Jun-Biao Chang(*). Highly Enantioselective Catalytic System for Asymmetric Copolymerization of Carbon Dioxide and Cyclohexene Oxide[J]. Chem.–Eur. J. 2014, 20, 12394–12398.
14. Yuan-Zhao Hua, Xing-Wang Han, Xiao-Chao Yang, Xixi Song, Min-Can Wang(*), and Jun-Biao Chang(*). Enantioselective Friedel−Crafts Alkylation of Pyrrole with Chalcones Catalyzed by a Dinuclear Zinc Catalyst[J]. J. Org. Chem. 2014, 79, 11690–11699.
专利申请：
1. 华远照，杨小超，王瑞丽，刘萌萌，耿宇欢，郭亚军，王敏灿。一种手性氮杂半冠醚多齿配体及其制备方法与应用。中国专利，申请号：201910425729.6
2. 华远照，杨小超，耿宇欢，刘萌萌，王瑞丽，郭亚军，王敏灿。一种手性3,2’-四氢吡咯双螺氧化吲哚衍生物及其制备方法。中国专利，申请号：201910424305.8
